48.0.13
Page 1/6
Safety data sheet according to 1907/2006/EC, Article 31 Printing date 05.02.2019 *
Version number 14
Revision: 05.02.2019
SECTION 1: Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: AQUAFIN-CA · 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture Adhesives · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: SCHOMBURG GmbH & Co. KG Aquafinstr. 2-8 D-32760 Detmold Germany ---------------------------------------------Tel: ++49 (0)5231/953-00 Fax: ++49 (0)5231/953-123 email: info@schomburg.de web: www.schomburg.de · Informing department: Product Safety Department Tel: ++49 (0)5231/953-193 Fax: ++49 (0)5231/953-106 email: guido.herfort@schomburg.de
*
SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 The product is not classified, according to the CLP regulation. · 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 Void · Hazard pictograms Void · Signal word Void · Hazard statements Void · Precautionary statements P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P363 Wash contaminated clothing before reuse. P370+P378 In case of fire: Use for extinction: CO2, powder or water spray. · Additional information: Safety data sheet available on request. · 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable.
SECTION 3: Composition/information on ingredients · 3.2 Chemical characterisation: Mixtures · Description: Solvent containing preparation based on synthetic rubber. · Dangerous components: CAS: 2768-02-7 vinyltrimethoxysilane EINECS: 220-449-8 Acute Tox. 4, H332 · Additional information For the wording of the listed hazard phrases refer to section 16.
<2.5%
GB
(Contd. on page 2)
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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 05.02.2019
Trade name: AQUAFIN-CA (Contd. of page 1)
SECTION 4: First aid measures · 4.1 Description of first aid measures · General information Personal protection for the First Aider. · After inhalation Supply fresh air or oxygen; call for doctor. · After skin contact Wash with water and soap. · After eye contact Rinse opened eye for several minutes under running water. · After swallowing Do not induce vomiting; instantly call for medical help. A person vomiting while lying on their back should be turned onto their side. · 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents CO2, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-resistant foam. · 5.2 Special hazards arising from the substance or mixture Can form explosive gas-air mixtures. · 5.3 Advice for firefighters · Protective equipment: Wear self-contained breathing apparatus. · Additional information Follow the emergency-plan. SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Keep away from ignition sources Ensure adequate ventilation Wear protective equipment. Keep unprotected persons away. · 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. · 6.3 Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). · 6.4 Reference to other sections See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. See Section 13 for information on disposal. SECTION 7: Handling and storage · 7.1 Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. Keep away from children. · Information about protection against explosions and fires: Keep ignition sources away - Do not smoke. · 7.2 Conditions for safe storage, including any incompatibilities · Storage · Requirements to be met by storerooms and containers: No special requirements. · Information about storage in one common storage facility: Please follow the rules of the VCI-Storage-Concept for chemicals. · Further information about storage conditions: Keep container tightly sealed. Do not store in restrooms or dining-rooms.
(Contd. on page 3) GB
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Trade name: AQUAFIN-CA
· 7.3 Specific end use(s) No further relevant information available. *
(Contd. of page 2)
SECTION 8: Exposure controls/personal protection · Additional information about design of technical systems: It must be possible to wash the skin in the working area. Eye-wash bottle must be available. · 8.1 Control parameters · Components with critical values that require monitoring at the workplace: 123-86-4 n-butyl acetate (10-25%) WEL Short-term value: 966 mg/m³, 200 ppm Long-term value: 724 mg/m³, 150 ppm · Additional information: The lists that were valid during the compilation were used as basis. · 8.2 Exposure controls · Personal protective equipment · General protective and hygienic measures The usual precautionary measures should be adhered to in handling the chemicals. Do not eat, drink or smoke while working. Be sure to clean skin thoroughly after work and before breaks. · Breathing equipment: Not required. · Protection of hands: Hand Protection: Nitril-rubber-latex-gloves. · Material of gloves Butyl rubber II R: Thickness ≥ 0,5mm; Break through time ≥ 480 min · Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye protection: Safety glasses · Body protection: Protective work clothing.
SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Appearance: Form: Pasty Colour: According to product specification · Smell: Mild · Change in condition Melting point/freezing point: Not determined Initial boiling point and boiling range: Not determined · Flash point:
>100 °C
· Ignition temperature:
435 °C
· Self-inflammability:
Product is not selfigniting.
· Explosive properties:
Product is not explosive. However, formation of explosive air/steam mixtures is possible.
· Critical values for explosion: Lower: Upper:
Not determined. Not determined.
· Steam pressure:
Not determined. (Contd. on page 4) GB
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Trade name: AQUAFIN-CA (Contd. of page 3)
· Density at 20 °C
1.5 g/cm³
· Solubility in / Miscibility with Water:
Unsoluble
· Viscosity: dynamic: · 9.2 Other information
Not determined. No further relevant information available.
SECTION 10: Stability and reactivity · 10.1 Reactivity No further relevant information available. · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · 10.3 Possibility of hazardous reactions No dangerous reactions known · 10.4 Conditions to avoid No further relevant information available. · 10.5 Incompatible materials: Strong oxidationresorts · 10.6 Hazardous decomposition products: Inflammable gases/vapours *
SECTION 11: Toxicological information · 11.1 Information on toxicological effects · Acute toxicity Based on available data, the classification criteria are not met. · LD/LC50 values that are relevant for classification: No dates existing. · Primary irritant effect: No irritant action known. · Skin corrosion/irritation Based on available data, the classification criteria are not met. · Serious eye damage/irritation Based on available data, the classification criteria are not met. · Respiratory or skin sensitisation Based on available data, the classification criteria are not met. · CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) · Germ cell mutagenicity Based on available data, the classification criteria are not met. · Carcinogenicity Based on available data, the classification criteria are not met. · Reproductive toxicity Based on available data, the classification criteria are not met. · STOT-single exposure Based on available data, the classification criteria are not met. · STOT-repeated exposure Based on available data, the classification criteria are not met. · Aspiration hazard Based on available data, the classification criteria are not met. SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: No further relevant information available. · 12.2 Persistence and degradability No further relevant information available. · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · Additional ecological information: · General notes: Water hazard class 1 (Self-assessment): slightly hazardous for water. · 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · 12.6 Other adverse effects No further relevant information available. GB
(Contd. on page 5)
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Trade name: AQUAFIN-CA (Contd. of page 4)
SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system. · European waste catalogue 08 00 00 WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) OF COATINGS (PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVES, SEALANTS AND PRINTING INKS 08 04 00 wastes from MFSU of adhesives and sealants (including waterproofing products) 08 04 09 waste adhesives and sealants containing organic solvents or other dangerous substances · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. SECTION 14: Transport information · 14.1 UN-Number · ADR, IMDG, IATA · ADN
UN1133 Void
· 14.2 UN proper shipping name · ADR · ADN · IMDG · IATA
UN1133 Void ADHESIVES ADHESIVES mixture
· 14.3 Transport hazard class(es) · ADR, ADN, IMDG · Class
Void
· IATA
· Class · Label
3 Flammable liquids. 3
· 14.4 Packing group · ADR, IMDG · IATA
Void III
· 14.5 Environmental hazards: · Marine pollutant:
No
· 14.6 Special precautions for user · EMS Number:
Not applicable. F-E,S-D
· 14.7 Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable. · Transport/Additional information: · ADR · Remarks:
> 450 l: 3 F1, III (Contd. on page 6) GB
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Trade name: AQUAFIN-CA (Contd. of page 5)
· IMDG · Remarks: · UN "Model Regulation":
Beförderung in Übereinstimmung mit dem IMDG CODE 2.3.2.5 Void
SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · Directive 2012/18/EU · Qualifying quantity (tonnes) for the application of lower-tier requirements 5.000 t · Qualifying quantity (tonnes) for the application of upper-tier requirements 50.000 t · National regulations · Technical instructions (air): · Class Share in % · NK 30.0 · Water hazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water. The classification based on german instructions. · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. SECTION 16: Other information These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases H332 Harmful if inhaled. · Department issuing data specification sheet: Environment protection department. · Contact: Mr. Guido Herfort · Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative Acute Tox. 4: Acute toxicity – Category 4
· * Data compared to the previous version altered.