ASO-R005_-_206400_(24)EN.pdf
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<h1>ASO-R005_-_206400_(24)EN.pdf</h1> <p>51.0.11</p> <p>Page 1/8</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 25.06.2020</p> <p>Version number 24</p> <p>Revision: 25.06.2020</p> <p>SECTION 1: Identification of the substance/mixture and of the company/undertaking <br />· 1.1 Product identifier <br />· Trade name: ASO-R005 <br />· 1.2 Relevant identified uses of the substance or mixture and uses advised against <br />No further relevant information available. <br />· Application of the substance / the mixture Cleaning agent/ Cleaner <br />· 1.3 Details of the supplier of the safety data sheet <br />· Manufacturer/Supplier: <br />SCHOMBURG GmbH & Co. KG <br />Aquafinstr. 2-8 <br />D-32760 Detmold <br />Germany <br />---------------------------------------------Tel: ++49 (0)5231/953-00 <br />Fax: ++49 (0)5231/953-123 <br />email: info@schomburg.de <br />web: www.schomburg.de <br />· Informing department: <br />Product Safety Department <br />Tel: ++49 (0)5231/953-193 <br />Fax: ++49 (0)5231/953-106 <br />email: SDB@schomburg.de <br />SECTION 2: Hazards identification <br />· 2.1 Classification of the substance or mixture <br />· Classification according to Regulation (EC) No 1272/2008 <br />GHS05 corrosion <br />Met. Corr.1 H290 May be corrosive to metals. <br />Skin Corr. 1B H314 Causes severe skin burns and eye damage. <br />Eye Dam. 1 H318 Causes serious eye damage. <br />GHS07 <br />Acute Tox. 4 H302 Harmful if swallowed. <br />Acute Tox. 4 H332 Harmful if inhaled. <br />· 2.2 Label elements <br />· Labelling according to Regulation (EC) No 1272/2008 <br />The product is classified and labelled according to the CLP regulation. <br />· Hazard pictograms GHS05, GHS07 <br />· Signal word Danger <br />· Hazard-determining components of labelling: <br />formic acid <br />· Hazard statements <br />H290 <br />May be corrosive to metals. <br />H302+H332 Harmful if swallowed or if inhaled. <br />(Contd. on page 2) <br />GB</p> <p>51.0.11</p> <p>Page 2/8</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 25.06.2020</p> <p>Version number 24</p> <p>Revision: 25.06.2020</p> <p>Trade name: ASO-R005 <br />(Contd. of page 1)</p> <p>H314 <br />Causes severe skin burns and eye damage. <br />· Precautionary statements <br />P260 <br />Do not breathe dusts or mists. <br />P280 <br />Wear protective gloves/protective clothing/eye protection/face protection/hearing <br />protection. <br />P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with <br />water [or shower]. <br />P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, <br />if present and easy to do. Continue rinsing. <br />P405 <br />Store locked up. <br />P501 <br />Dispose of contents/container in accordance with local/regional/national/international <br />regulations. <br />· 2.3 Other hazards <br />· Results of PBT and vPvB assessment <br />· PBT: Not applicable. <br />· vPvB: Not applicable. <br />*</p> <p>SECTION 3: Composition/information on ingredients <br />· 3.2 Chemical characterisation: Mixtures <br />· Description: Aqueous solution of an organic acid. <br />· Dangerous components: <br />CAS: 64-18-6 <br />formic acid <br />EINECS: 200-579-1 <br />Flam. Liq. 3, H226; <br />Acute Tox. 3, H331; <br />Met. Corr.1, H290; Skin <br />Corr. 1A, H314; Eye Dam. 1, H318; <br />Acute Tox. 4, H302 <br />· Additional information For the wording of the listed hazard phrases refer to section 16.</p> <p>25-50%</p> <p>SECTION 4: First aid measures <br />· 4.1 Description of first aid measures <br />· General information <br />Personal protection for the First Aider. <br />Instantly remove any clothing soiled by the product. <br />Symptoms of poisoning may even occur after several hours; therefore medical observation for at least <br />48 hours after the accident. <br />Personal protection for the First Aider. <br />It is possible to choke in case of vomiting in unconsciousness. <br />Bring unconscious persons into a stable position on side. <br />Keep the respiratory tract free (remove dentures and vomiting). <br />Check the pulse. In case of heart failure you have to make a cardiac massage. In case of stoppage of <br />breathing: artificial respiration. <br />Take up a doctor immediately! <br />· After inhalation Supply fresh air or oxygen; call for doctor. <br />· After skin contact Wash with water and soap. <br />· After eye contact Rinse opened eye for several minutes under running water. Then consult doctor. <br />· After swallowing <br />Drink copious amounts of water and provide fresh air. Instantly call for doctor. <br />Show the pack or the label to the doctor. <br />· 4.2 Most important symptoms and effects, both acute and delayed <br />No further relevant information available.</p> <p>(Contd. on page 3) <br />GB</p> <p>51.0.11</p> <p>Page 3/8</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 25.06.2020</p> <p>Version number 24</p> <p>Revision: 25.06.2020</p> <p>Trade name: ASO-R005</p> <p>· 4.3 Indication of any immediate medical attention and special treatment needed <br />No further relevant information available.</p> <p>(Contd. of page 2)</p> <p>SECTION 5: Firefighting measures <br />· 5.1 Extinguishing media <br />· Suitable extinguishing agents <br />Product is not inflammable. <br />CO2, extinguishing powder or water jet. Fight larger fires with water jet. <br />· 5.2 Special hazards arising from the substance or mixture <br />Formation of poisonous gases during heating or in fires. <br />· 5.3 Advice for firefighters <br />· Protective equipment: Wear PVC-boots, protective gloves and clothing. <br />· Additional information <br />Collect contaminated fire fighting water separately. It must not enter drains. <br />Follow the emergency-plan. <br />SECTION 6: Accidental release measures <br />· 6.1 Personal precautions, protective equipment and emergency procedures <br />Bring persons out of danger. <br />Wear protective equipment. Keep unprotected persons away. <br />· 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. <br />· 6.3 Methods and material for containment and cleaning up: <br />Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). <br />Use neutralising agent. <br />Ensure adequate ventilation. <br />· 6.4 Reference to other sections <br />See Section 7 for information on safe handling <br />See Section 8 for information on personal protection equipment. <br />See Section 13 for information on disposal. <br />SECTION 7: Handling and storage <br />· 7.1 Precautions for safe handling <br />Ensure good ventilation/exhaustion at the workplace. <br />Prevent formation of aerosols. <br />Keep away from children. <br />· Information about protection against explosions and fires: No special measures required. <br />· 7.2 Conditions for safe storage, including any incompatibilities <br />· Storage <br />· Requirements to be met by storerooms and containers: No special requirements. <br />· Information about storage in one common storage facility: <br />Please follow the rules of the VCI-Storage-Concept for chemicals. <br />· Further information about storage conditions: <br />Protect from frost. <br />Keep container tightly sealed. <br />Store in a locked cabinet and out of the reach of children. <br />· 7.3 Specific end use(s) No further relevant information available. <br />GB</p> <p>(Contd. on page 4)</p> <p>51.0.11</p> <p>Page 4/8</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 25.06.2020</p> <p>Version number 24</p> <p>Revision: 25.06.2020</p> <p>Trade name: ASO-R005 <br />(Contd. of page 3)</p> <p>SECTION 8: Exposure controls/personal protection <br />· Additional information about design of technical systems: <br />It must be possible to wash the skin in the working area. <br />Eye-wash bottle must be available. <br />· 8.1 Control parameters <br />· Components with critical values that require monitoring at the workplace: <br />64-18-6 formic acid (25-50%) <br />WEL Long-term value: 9.6 mg/m³, 5 ppm <br />· Additional information: The lists that were valid during the compilation were used as basis. <br />· 8.2 Exposure controls <br />· Personal protective equipment <br />· General protective and hygienic measures <br />Wash hands during breaks and at the end of the work. <br />The usual precautionary measures should be adhered to in handling the chemicals. <br />Instantly remove any soiled and impregnated garments. <br />Avoid contact with the eyes and skin. <br />Be sure to clean skin thoroughly after work and before breaks. <br />· Breathing equipment: Use breathing protection in case of insufficient ventilation. <br />· Protection of hands: Hand Protection: Nitril-rubber-latex-gloves. <br />· Material of gloves <br />Nitrile coated protective gloves (category III, material strength: 0,425 mm break through time > 480 Min <br />(eg. Ansell Chemical Protective gloves Sol-Vex® 37-900) <br />· Penetration time of glove material <br />The exact break trough time has to be found out by the manufacturer of the protective gloves and has to <br />be observed. <br />· Eye protection: Safety glasses <br />· Body protection: Protective work clothing. <br />SECTION 9: Physical and chemical properties <br />· 9.1 Information on basic physical and chemical properties <br />· General Information <br />· Appearance: <br />Form: <br />Fluid <br />Colour: <br />Colourless <br />· Smell: <br />Odourless <br />· Odour threshold: <br />Not determined. <br />· pH-value at 20 °C:</p> <p>2.2</p> <p>· Change in condition <br />Melting point/freezing point: <br />-13 °C <br />Initial boiling point and boiling range: >100 °C <br />· Flash point:</p> <p>62 °C</p> <p>· Inflammability (solid, gaseous)</p> <p>Not applicable.</p> <p>· Decomposition temperature:</p> <p>Not determined.</p> <p>· Self-inflammability:</p> <p>Product is not selfigniting.</p> <p>· Explosive properties:</p> <p>Product is not explosive. <br />(Contd. on page 5) <br />GB</p> <p>51.0.11</p> <p>Page 5/8</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 25.06.2020</p> <p>Version number 24</p> <p>Revision: 25.06.2020</p> <p>Trade name: ASO-R005 <br />(Contd. of page 4)</p> <p>· Critical values for explosion: <br />Lower: <br />Upper:</p> <p>14.9 Vol % <br />47.6 Vol %</p> <p>· Steam pressure at 20 °C:</p> <p>21 hPa</p> <p>· Density at 20 °C <br />· Relative density <br />· Vapour density <br />· Evaporation rate</p> <p>1.2 g/cm³ <br />1.6 <br />Not determined. <br />Not determined.</p> <p>· Solubility in / Miscibility with <br />Water:</p> <p>miscible</p> <p>· Partition coefficient: n-octanol/water:</p> <p>Not determined.</p> <p>· Viscosity: <br />dynamic at 20 °C: <br />kinematic: <br />· 9.2 Other information</p> <p>1.6 mPas <br />Not determined. <br />No further relevant information available.</p> <p>SECTION 10: Stability and reactivity <br />· 10.1 Reactivity No further relevant information available. <br />· 10.2 Chemical stability <br />· Thermal decomposition / conditions to be avoided: <br />No decomposition if used according to specifications. <br />· 10.3 Possibility of hazardous reactions No dangerous reactions known <br />· 10.4 Conditions to avoid No further relevant information available. <br />· 10.5 Incompatible materials: No further relevant information available. <br />· 10.6 Hazardous decomposition products: No dangerous decomposition products known <br />SECTION 11: Toxicological information <br />· 11.1 Information on toxicological effects <br />· Acute toxicity <br />Harmful if swallowed or if inhaled. <br />· LD/LC50 values that are relevant for classification: <br />64-18-6 formic acid <br />Oral <br />LD50 <br />730 mg/kg (rats) (OECD 401) <br />Inhalative LC50/4 h 7.85 mg/l (rats) (OECD 403) <br />· Primary irritant effect: <br />· Skin corrosion/irritation <br />Causes severe skin burns and eye damage. <br />· Serious eye damage/irritation <br />Causes serious eye damage. <br />· Respiratory or skin sensitisation Based on available data, the classification criteria are not met. <br />· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) <br />· Germ cell mutagenicity Based on available data, the classification criteria are not met. <br />· Carcinogenicity Based on available data, the classification criteria are not met. <br />· Reproductive toxicity Based on available data, the classification criteria are not met. <br />· STOT-single exposure Based on available data, the classification criteria are not met.</p> <p>(Contd. on page 6) <br />GB</p> <p>51.0.11</p> <p>Page 6/8</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 25.06.2020</p> <p>Version number 24</p> <p>Revision: 25.06.2020</p> <p>Trade name: ASO-R005</p> <p>· STOT-repeated exposure Based on available data, the classification criteria are not met. <br />· Aspiration hazard Based on available data, the classification criteria are not met.</p> <p>(Contd. of page 5)</p> <p>SECTION 12: Ecological information <br />· 12.1 Toxicity <br />· Aquatic toxicity: <br />64-18-6 formic acid <br />LC50/96h <br />1,720 mg/l (fish toxicity) <br />EC/LC50 (48h) 365 mg/l (Daphnia magna) (OECD 202) <br />EC/LC50 (17h) 46.7 mg/l (bacterial toxicity) <br />ERC50 <br />1,240 mg/l /72h (Pseudokirchneriella subcapitata) <br />LOEC <br />≥100 mg/l /21d (Daphnia magna) (OECD 211) <br />NOEC <br />≥100 mg/l /21d (Daphnia magna) (OECD 211) <br />· 12.2 Persistence and degradability No further relevant information available. <br />· 12.3 Bioaccumulative potential No further relevant information available. <br />· 12.4 Mobility in soil No further relevant information available. <br />· Additional ecological information: <br />· General notes: <br />Water hazard class 1 (Self-assessment): slightly hazardous for water. <br />Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage <br />system. <br />Must not reach sewage water or drainage ditch undiluted or unneutralised. <br />Rinse off of bigger amounts into drains or the aquatic environment may lead to decreased pH-values. A <br />low pH-value harms aquatic organisms. In the dilution of the use-level the pH-value is considerably <br />increased, so that after the use of the product the aqueous waste, emptied into drains, is only low waterdangerous. <br />· 12.5 Results of PBT and vPvB assessment <br />· PBT: Not applicable. <br />· vPvB: Not applicable. <br />· 12.6 Other adverse effects No further relevant information available. <br />SECTION 13: Disposal considerations <br />· 13.1 Waste treatment methods <br />· Recommendation <br />Must not be disposed of together with household garbage. Do not allow product to reach sewage <br />system. <br />· European waste catalogue <br />07 00 00 WASTES FROM ORGANIC CHEMICAL PROCESSES <br />07 01 00 wastes from the manufacture, formulation, supply and use (MFSU) of basic organic chemicals <br />07 01 99 wastes not otherwise specified <br />· Uncleaned packagings: <br />· Recommendation: Disposal must be made according to official regulations. <br />· Recommended cleaning agent: Water, if necessary with cleaning agent. <br />GB</p> <p>(Contd. on page 7)</p> <p>51.0.11</p> <p>Page 7/8</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 25.06.2020</p> <p>Version number 24</p> <p>Revision: 25.06.2020</p> <p>Trade name: ASO-R005 <br />(Contd. of page 6)</p> <p>*</p> <p>SECTION 14: Transport information <br />· 14.1 UN-Number <br />· ADR, IMDG, IATA</p> <p>UN3412</p> <p>· 14.2 UN proper shipping name <br />· ADR <br />· IMDG, IATA</p> <p>3412 FORMIC ACID <br />FORMIC ACID</p> <p>· 14.3 Transport hazard class(es) <br />· ADR, IMDG, IATA</p> <p>· Class <br />· Label</p> <p>8 Corrosive substances. <br />8</p> <p>· 14.4 Packing group <br />· ADR, IMDG, IATA</p> <p>II</p> <p>· 14.5 Environmental hazards:</p> <p>Not applicable.</p> <p>· 14.6 Special precautions for user <br />· Kemler Number: <br />· EMS Number: <br />· Segregation groups <br />· Stowage Category <br />· Stowage Code</p> <p>Warning: Corrosive substances. <br />80 <br />F-A,S-B <br />Acids <br />A <br />SW2 Clear of living quarters.</p> <p>· 14.7 Transport in bulk according to Annex II of <br />Marpol and the IBC Code <br />Not applicable. <br />· Transport/Additional information: <br />· ADR <br />· Limited quantities (LQ) <br />· Excepted quantities (EQ) <br />· Transport category <br />· Tunnel restriction code <br />· IMDG <br />· Limited quantities (LQ) <br />· Excepted quantities (EQ)</p> <p>· UN "Model Regulation":</p> <p>1L <br />Code: E2 <br />Maximum net quantity per inner packaging: 30 ml <br />Maximum net quantity per outer packaging: 500 ml <br />2 <br />E <br />1L <br />Code: E2 <br />Maximum net quantity per inner packaging: 30 ml <br />Maximum net quantity per outer packaging: 500 ml <br />UN 3412 FORMIC ACID, 8, II <br />GB</p> <p>(Contd. on page 8)</p> <p>51.0.11</p> <p>Page 8/8</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 25.06.2020</p> <p>Version number 24</p> <p>Revision: 25.06.2020</p> <p>Trade name: ASO-R005 <br />(Contd. of page 7)</p> <p>SECTION 15: Regulatory information <br />· 15.1 Safety, health and environmental regulations/legislation specific for the substance or <br />mixture <br />· Directive 2012/18/EU <br />· Named dangerous substances - ANNEX I None of the ingredients is listed. <br />· REGULATION (EC) No 1907/2006 ANNEX XVII Conditions of restriction: 3 <br />· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. <br />SECTION 16: Other information <br />These data are based on our present knowledge. However, they shall not constitute a guarantee for any <br />specific product features and shall not establish a legally valid contractual relationship. <br />· Relevant phrases <br />H226 Flammable liquid and vapour. <br />H290 May be corrosive to metals. <br />H302 Harmful if swallowed. <br />H314 Causes severe skin burns and eye damage. <br />H318 Causes serious eye damage. <br />H331 Toxic if inhaled. <br />· Department issuing data specification sheet: Environment protection department. <br />· Contact: Mr. Guido Herfort <br />· Abbreviations and acronyms: <br />ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the <br />International Carriage of Dangerous Goods by Road) <br />IMDG: International Maritime Code for Dangerous Goods <br />IATA: International Air Transport Association <br />GHS: Globally Harmonised System of Classification and Labelling of Chemicals <br />EINECS: European Inventory of Existing Commercial Chemical Substances <br />ELINCS: European List of Notified Chemical Substances <br />CAS: Chemical Abstracts Service (division of the American Chemical Society) <br />LC50: Lethal concentration, 50 percent <br />LD50: Lethal dose, 50 percent <br />PBT: Persistent, Bioaccumulative and Toxic <br />vPvB: very Persistent and very Bioaccumulative <br />Flam. Liq. 3: Flammable liquids – Category 3 <br />Met. Corr.1: Corrosive to metals – Category 1 <br />Acute Tox. 4: Acute toxicity - oral – Category 4 <br />Acute Tox. 3: Acute toxicity - inhalation – Category 3 <br />Skin Corr. 1A: Skin corrosion/irritation – Category 1A <br />Skin Corr. 1B: Skin corrosion/irritation – Category 1B <br />Eye Dam. 1: Serious eye damage/eye irritation – Category 1</p> <p>· * Data compared to the previous version altered.</p> <p>GB</p>
