44.0
Page 1/7
Safety data sheet according to 1907/2006/EC, Article 31 Printing date 05.01.2017 *
Version number 6
Revision: 05.01.2017
SECTION 1: Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: ASODUR-B 351 (B-Komp.)(INDUFLOOR-IB 3357 (B-Komp.)) · Article number: 205796B · 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture Hardening agent/ Curing agent · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: SCHOMBURG GmbH & Co. KG Aquafinstr. 2-8 D-32760 Detmold Germany ---------------------------------------------Tel: ++49 (0)5231/953-00 Fax: ++49 (0)5231/953-123 email: info@schomburg.de web: www.schomburg.de · Informing department: Product Safety Department Tel: ++49 (0)5231/953-193 Fax: ++49 (0)5231/953-106 email: guido.herfort@schomburg.de
*
SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 GHS05 corrosion Skin Corr. 1B Eye Dam. 1
H314 Causes severe skin burns and eye damage. H318 Causes serious eye damage.
GHS07 Acute Tox. 4 Skin Sens. 1
H302 Harmful if swallowed. H317 May cause an allergic skin reaction.
Aquatic Chronic 3 H412 Harmful to aquatic life with long lasting effects. · 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the CLP regulation. · Hazard pictograms GHS05, GHS07 · Signal word Danger · Hazard-determining components of labelling: 3-aminomethyl-3,5,5-trimethylcyclohexylamine Benzyl alcohol Salicylic acid · Hazard statements H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. (Contd. on page 2) GB
Page 2/7
Safety data sheet according to 1907/2006/EC, Article 31 Printing date 05.01.2017
Trade name: ASODUR-B 351 (B-Komp.)(INDUFLOOR-IB 3357 (B-Komp.)) (Contd. of page 1)
H412 Harmful to aquatic life with long lasting effects. · Precautionary statements P273 Avoid release to the environment. P260 Do not breathe dusts or mists. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national/ international regulations. · 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. *
SECTION 3: Composition/information on ingredients · 3.2 Chemical characterisation: Mixtures · Description: Modified cycloaliphatic Polyamine · Dangerous components: CAS: 100-51-6 Benzyl alcohol EINECS: 202-859-9 Acute Tox. 4, H302; Acute Tox. 4, H332; Eye Irrit. 2, H319
25-50%
CAS: 2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine EINECS: 220-666-8 Skin Corr. 1B, H314; Acute Tox. 4, H302; Acute Tox. 4, H312; Skin Sens. 1, H317; Aquatic Chronic 3, H412
CAS: 69-72-7 Salicylic acid EINECS: 200-712-3 Eye Dam. 1, H318
2.5-10%
SECTION 4: First aid measures · 4.1 Description of first aid measures · General information Instantly remove any clothing soiled by the product. Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. Personal protection for the First Aider. It is possible to choke in case of vomiting in unconsciousness. Bring unconscious persons into a stable position on side. Keep the respiratory tract free (remove dentures and vomiting). Check the pulse. In case of heart failure you have to make a cardiac massage. In case of stoppage of breathing: artificial respiration. Take up a doctor immediately! · After inhalation Supply fresh air or oxygen; call for doctor. · After skin contact Instantly wash with water and soap and rinse thoroughly. · After eye contact Rinse opened eye for several minutes under running water. Then consult doctor. · After swallowing Instantly call for doctor. Drink copious amounts of water and provide fresh air. Instantly call for doctor. · 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. GB
(Contd. on page 3)
Page 3/7
Trade name: ASODUR-B 351 (B-Komp.)(INDUFLOOR-IB 3357 (B-Komp.)) (Contd. of page 2)
SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents Use fire fighting measures that suit the environment. · 5.2 Special hazards arising from the substance or mixture No further relevant information available. · 5.3 Advice for firefighters · Protective equipment: Put on breathing apparatus. *
SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Wear protective equipment. Keep unprotected persons away. · 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. · 6.3 Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Use neutralising agent. Ensure adequate ventilation. · 6.4 Reference to other sections See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. See Section 13 for information on disposal. SECTION 7: Handling and storage · 7.1 Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. · Information about protection against explosions and fires: No special measures required. · 7.2 Conditions for safe storage, including any incompatibilities · Storage · Requirements to be met by storerooms and containers: Store in cool location. · Information about storage in one common storage facility: Please follow the rules of the VCI-Storage-Concept for chemicals. · Further information about storage conditions: Keep container tightly sealed. · 7.3 Specific end use(s) No further relevant information available.
SECTION 8: Exposure controls/personal protection · Additional information about design of technical systems: No further data; see item 7 MSDS. · 8.1 Control parameters · Components with critical values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. · Additional information: The lists that were valid during the compilation were used as basis. · 8.2 Exposure controls · Personal protective equipment · General protective and hygienic measures The usual precautionary measures should be adhered to in handling the chemicals. Keep away from foodstuffs, beverages and food. Instantly remove any soiled and impregnated garments. Wash hands during breaks and at the end of the work. Avoid contact with the eyes and skin. · Breathing equipment: Not required. · Protection of hands: Hand Protection: Nitril-rubber-latex-gloves. (Contd. on page 4) GB
Page 4/7
Trade name: ASODUR-B 351 (B-Komp.)(INDUFLOOR-IB 3357 (B-Komp.)) (Contd. of page 3)
· Material of gloves Butyl rubber II R: Thickness ≥ 0,5mm; Break through time ≥ 480 min · Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye protection: Safety glasses · Body protection: Protective work clothing. SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Appearance: Form: Fluid Colour: Light yellow · Smell: Amine-like · pH-value at 20 °C:
10.8
· Change in condition Melting point/freezing point: Not determined Initial boiling point and boiling range: Not determined · Flash point:
131 °C
· Ignition temperature:
380 °C
· Self-inflammability:
Product is not selfigniting.
· Explosive properties:
Product is not explosive.
· Critical values for explosion: Lower: Upper:
1.3 Vol % 13.0 Vol %
· Steam pressure at 20 °C:
0.3 hPa
· Density at 20 °C
1.03 g/cm³
· Solubility in / Miscibility with Water:
Fully miscible
· Viscosity: dynamic at 20 °C:
450 mPas
· Solvent content: Organic solvents: · 9.2 Other information
42.5 % No further relevant information available.
SECTION 10: Stability and reactivity · 10.1 Reactivity No further relevant information available. · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · 10.3 Possibility of hazardous reactions No dangerous reactions known · 10.4 Conditions to avoid No further relevant information available. · 10.5 Incompatible materials: No further relevant information available. (Contd. on page 5) GB
Page 5/7
Trade name: ASODUR-B 351 (B-Komp.)(INDUFLOOR-IB 3357 (B-Komp.)) (Contd. of page 4)
· 10.6 Hazardous decomposition products: No dangerous decomposition products known *
SECTION 11: Toxicological information · 11.1 Information on toxicological effects · Acute toxicity Harmful if swallowed. · LD/LC50 values that are relevant for classification: 100-51-6 Benzyl alcohol Oral LD50 1570 mg/kg (rats) Inhalative LC50 11 mg/l 2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine Oral LD50 1030 mg/kg (rats) Dermal LD50 1840 mg/kg (rats) 69-72-7 Salicylic acid Oral LD50 >2000 mg/kg (rabbit) LD50 891 mg/kg (rats) · Primary irritant effect: · Skin corrosion/irritation Causes severe skin burns and eye damage. · Serious eye damage/irritation Causes serious eye damage. · Respiratory or skin sensitisation May cause an allergic skin reaction. · CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) · Germ cell mutagenicity Based on available data, the classification criteria are not met. · Carcinogenicity Based on available data, the classification criteria are not met. · Reproductive toxicity Based on available data, the classification criteria are not met. · STOT-single exposure Based on available data, the classification criteria are not met. · STOT-repeated exposure Based on available data, the classification criteria are not met. · Aspiration hazard Based on available data, the classification criteria are not met.
SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: 69-72-7 Salicylic acid LC50/96h 1380 mg/l (fish toxicity) EC50 (48h) 870 mg/l (Daphnia magna) · 12.2 Persistence and degradability No further relevant information available. · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · Additional ecological information: · General notes: Water hazard class 1 (Self-assessment): slightly hazardous for water. Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage system. Must not reach sewage water or drainage ditch undiluted or unneutralised. · 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. (Contd. on page 6) GB
Page 6/7
Trade name: ASODUR-B 351 (B-Komp.)(INDUFLOOR-IB 3357 (B-Komp.)) (Contd. of page 5)
· 12.6 Other adverse effects No further relevant information available. SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system. · European waste catalogue 07 00 00 WASTES FROM ORGANIC CHEMICAL PROCESSES 07 02 00 wastes from the MFSU of plastics, synthetic rubber and man-made fibres 07 02 99 wastes not otherwise specified 07 00 00 WASTES FROM ORGANIC CHEMICAL PROCESSES 07 02 00 wastes from the MFSU of plastics, synthetic rubber and man-made fibres 07 02 04* other organic solvents, washing liquids and mother liquors · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. · Recommended cleaning agent: Water, if necessary with cleaning agent. *
SECTION 14: Transport information · 14.1 UN-Number · ADR, IMDG, IATA · 14.2 UN proper shipping name · ADR · IMDG, IATA
UN2735 2735 AMINES, LIQUID, CORROSIVE, N.O.S. (ISOPHORONEDIAMINE) AMINES, LIQUID, CORROSIVE, N.O.S. (ISOPHORONEDIAMINE)
· 14.3 Transport hazard class(es) · ADR, IMDG, IATA
· Class · Label
8 Corrosive substances. 8
· 14.4 Packing group · ADR, IMDG, IATA
III
· 14.5 Environmental hazards: · Marine pollutant: · 14.6 Special precautions for user · Kemler Number: · EMS Number: · Segregation groups
ja No Warning: Corrosive substances. 80 F-A,S-B Alkalis
· 14.7 Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable. (Contd. on page 7) GB
Page 7/7
Trade name: ASODUR-B 351 (B-Komp.)(INDUFLOOR-IB 3357 (B-Komp.)) (Contd. of page 6)
· Transport/Additional information: · ADR · Limited quantities (LQ) · Transport category · Tunnel restriction code · UN "Model Regulation":
5L 3 E UN2735, AMINES, LIQUID, CORROSIVE, N.O.S. (ISOPHORONEDIAMINE), 8, III
SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · REGULATION (EC) No 1907/2006 ANNEX XVII Conditions of restriction: 3 · National regulations · Water hazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water. · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. *
SECTION 16: Other information These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases H302 Harmful if swallowed. H312 Harmful in contact with skin. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H319 Causes serious eye irritation. H332 Harmful if inhaled. H412 Harmful to aquatic life with long lasting effects. · Department issuing data specification sheet: Environment protection department. · Contact: Mr. Guido Herfort · Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative Acute Tox. 4: Acute toxicity – Category 4 Skin Corr. 1B: Skin corrosion/irritation – Category 1B Eye Dam. 1: Serious eye damage/eye irritation – Category 1 Eye Irrit. 2: Serious eye damage/eye irritation – Category 2 Skin Sens. 1: Skin sensitisation – Category 1 Aquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard – Category 3
· * Data compared to the previous version altered. GB