50.0.4
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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 20.01.2020
Version number 1
Revision: 20.01.2020
SECTION 1: Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: ASODUR-GH-S (B-Komp.) · 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture Reaction resin · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: SCHOMBURG GmbH & Co. KG Aquafinstr. 2-8 D-32760 Detmold Germany ---------------------------------------------Tel: ++49 (0)5231/953-00 Fax: ++49 (0)5231/953-123 email: info@schomburg.de web: www.schomburg.de · Informing department: Product Safety Department Tel: ++49 (0)5231/953-193 Fax: ++49 (0)5231/953-106 email: SDB@schomburg.de SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 GHS08 health hazard Resp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. Carc. 2 H351 Suspected of causing cancer. STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure. GHS07 Acute Tox. 4 Skin Irrit. 2 Eye Irrit. 2 Skin Sens. 1 STOT SE 3
H332 Harmful if inhaled. H315 Causes skin irritation. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction. H335 May cause respiratory irritation.
· 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the CLP regulation. · Hazard pictograms GHS07, GHS08 · Signal word Danger
(Contd. on page 2) GB
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Trade name: ASODUR-GH-S (B-Komp.) (Contd. of page 1)
· Hazard-determining components of labelling: diphenylmethanediisocyanate,isomeres and homologues · Hazard statements H332 Harmful if inhaled. H315 Causes skin irritation. H319 Causes serious eye irritation. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H351 Suspected of causing cancer. H335 May cause respiratory irritation. H373 May cause damage to organs through prolonged or repeated exposure. · Precautionary statements P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P281 Use personal protective equipment as required. P302+P352 IF ON SKIN: Wash with plenty of water. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER/doctor. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. · Additional information: EUH204 Contains isocyanates. May produce an allergic reaction. · 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. SECTION 3: Composition/information on ingredients · 3.2 Chemical characterisation: Mixtures · Description: Produkt based on polyisocyanate. · Dangerous components: 9016-87-9 diphenylmethanediisocyanate,isomeres and homologues 50-100% Resp. Sens. 1, H334; Carc. 2, H351; STOT RE 2, H373; Acute Tox. 4, H332; Skin Irrit. 2, H315; Eye Irrit. 2, H319; Skin Sens. 1, H317; STOT SE 3, H335 · Additional information For the wording of the listed hazard phrases refer to section 16. SECTION 4: First aid measures · 4.1 Description of first aid measures · General information Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. Personal protection for the First Aider. It is possible to choke in case of vomiting in unconsciousness. Bring unconscious persons into a stable position on side. Keep the respiratory tract free (remove dentures and vomiting). Check the pulse. In case of heart failure you have to make a cardiac massage. In case of stoppage of breathing: artificial respiration. Take up a doctor immediately! · After inhalation Supply fresh air or oxygen; call for doctor. (Contd. on page 3) GB
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Trade name: ASODUR-GH-S (B-Komp.) (Contd. of page 2)
In case of unconsciousness bring patient into stable side position for transport. · After skin contact Instantly wash with water and soap and rinse thoroughly. Change immediately contaminated clothes. · After eye contact Rinse opened eye for several minutes under running water. If symptoms persist, consult doctor. · After swallowing Do not induce vomiting; instantly call for medical help. Show the pack or the label to the doctor. · 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. SECTION 5: Firefighting measures
· 5.1 Extinguishing media · Suitable extinguishing agents CO2, extinguishing powder or water jet. Fight larger fires with water jet. Use fire fighting measures that suit the environment. · 5.2 Special hazards arising from the substance or mixture Formation of poisonous gases during heating or in fires. Carbon monoxide (CO) Nitrogen oxides (NOx) Hydrogen cyanide (HCN) · 5.3 Advice for firefighters · Protective equipment: Wear self-contained breathing apparatus. Wear full protective suit. · Additional information Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. Follow the emergency-plan. Burst- and explosion-danger by increasing pressure. In case of fire chill the container with water spray. SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Wear protective equipment. Keep unprotected persons away. Ensure adequate ventilation · 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. · 6.3 Methods and material for containment and cleaning up: Ensure adequate ventilation. Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). · 6.4 Reference to other sections See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. See Section 13 for information on disposal. GB
(Contd. on page 4)
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Trade name: ASODUR-GH-S (B-Komp.) (Contd. of page 3)
SECTION 7: Handling and storage · 7.1 Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. Prevent formation of aerosols. · Information about protection against explosions and fires: No special measures required. · 7.2 Conditions for safe storage, including any incompatibilities · Storage · Requirements to be met by storerooms and containers: The Product reacts with water and CO2-Gas will be given off. In tight closed containers pressure may arise and the cover can burst. Store only in unopened original containers. · Information about storage in one common storage facility: Please follow the rules of the VCI-Storage-Concept for chemicals. Store away from water. Do not store together with oxidising and acidic materials. · Further information about storage conditions: Keep container tightly sealed. Store in a locked cabinet and out of the reach of children. Store under dry conditions. · 7.3 Specific end use(s) No further relevant information available. SECTION 8: Exposure controls/personal protection · Additional information about design of technical systems: No further data; see item 7 MSDS. · 8.1 Control parameters · Components with critical values that require monitoring at the workplace: 9016-87-9 diphenylmethanediisocyanate,isomeres and homologues (50-100%) WEL Short-term value: 0.07 mg/m³ Long-term value: 0.02 mg/m³ Sen; as -NCO · Additional information: The lists that were valid during the compilation were used as basis. · 8.2 Exposure controls · Personal protective equipment · General protective and hygienic measures The usual precautionary measures should be adhered to in handling the chemicals. Keep away from foodstuffs, beverages and food. Instantly remove any soiled and impregnated garments. Avoid contact with the eyes and skin. Be sure to clean skin thoroughly after work and before breaks. · Breathing equipment: In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or longer exposure use breathing apparatus that is independent of circulating air. · Protection of hands: Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation Hand Protection: Nitril-rubber-latex-gloves. · Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. (Contd. on page 5) GB
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Trade name: ASODUR-GH-S (B-Komp.)
Nitril-rubber-latex-gloves II R: Thickness 0,5mm; Break through time 480 min
(Contd. of page 4)
· Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye protection: Safety glasses · Body protection: Contaminated protection clothes must be cleaned carefully before reuse. Protective work clothing. SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Appearance: Form: Liquid Colour: Various colours · Smell: Weak, characteristic · Odour threshold: Not determined. · pH-value:
Not determined.
· Change in condition Melting point/freezing point: Not determined Initial boiling point and boiling range: >200 °C · Flash point:
>100 °C
· Inflammability (solid, gaseous)
Not applicable.
· Ignition temperature:
530 °C
· Decomposition temperature:
· Self-inflammability:
· Explosive properties:
Product is not explosive.
· Critical values for explosion: Lower: Upper:
Not determined. Not determined.
· Steam pressure:
· Density at 20 °C · Relative density · Vapour density · Evaporation rate
1.12 g/cm³ Not determined. Not determined. Not determined.
· Solubility in / Miscibility with Water:
Not miscible or difficult to mix
· Partition coefficient: n-octanol/water:
· Viscosity: dynamic at 20 °C: kinematic:
160 mPas Not determined. (Contd. on page 6) GB
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Trade name: ASODUR-GH-S (B-Komp.) (Contd. of page 5)
· 9.2 Other information
No further relevant information available.
SECTION 10: Stability and reactivity · 10.1 Reactivity No further relevant information available. · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · 10.3 Possibility of hazardous reactions No dangerous reactions known · 10.4 Conditions to avoid No further relevant information available. · 10.5 Incompatible materials: No further relevant information available. · 10.6 Hazardous decomposition products: No dangerous decomposition products known SECTION 11: Toxicological information · 11.1 Information on toxicological effects · Acute toxicity Harmful if inhaled. · LD/LC50 values that are relevant for classification: 9016-87-9 diphenylmethanediisocyanate,isomeres and homologues Oral LD50 >5,000 mg/kg (rats) Dermal LD50 >9,400 mg/kg (rabbit) (OECD Guideline 404) Inhalative LC50/4 h 0.49 mg/l (rats) (OECD Guideline 403) · Primary irritant effect: · Skin corrosion/irritation The product has an irritate-effect. Causes skin irritation. · Serious eye damage/irritation Causes serious eye irritation. · Respiratory or skin sensitisation May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. · CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) · Germ cell mutagenicity Based on available data, the classification criteria are not met. · Carcinogenicity Suspected of causing cancer. · Reproductive toxicity Based on available data, the classification criteria are not met. · STOT-single exposure May cause respiratory irritation. · STOT-repeated exposure May cause damage to organs through prolonged or repeated exposure. · Aspiration hazard Based on available data, the classification criteria are not met. SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: 9016-87-9 diphenylmethanediisocyanate,isomeres and homologues EC 50 >1,000 mg/kg (daphnia magna) (OECD Guideline 202)
(Contd. on page 7) GB
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Trade name: ASODUR-GH-S (B-Komp.) (Contd. of page 6)
>1,640 mg/kg (Grünalge (Scenedesmus subspicatus)) (OECD Guideline 201) LC50/96h >1,000 mg/l (zebra danio) (OECD Guideline 203) NOEC >10 mg/l (daphnia magna) (OECD Guideline 211) · 12.2 Persistence and degradability No further relevant information available. · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · Additional ecological information: · General notes: Water danger class 3 (Self-assessment): extremely hazardous for water. Do not allow product to reach ground water, water bodies or sewage system, even in small quantities. Danger to drinking water if even extremely small quantities leak into soil. · 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · 12.6 Other adverse effects No further relevant information available. SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system. · European waste catalogue 08 00 00 WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) OF COATINGS (PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVES, SEALANTS AND PRINTING INKS 08 05 00 wastes not otherwise specified in 08 08 05 01* waste isocyanates 15 00 00 WASTE PACKAGING; ABSORBENTS, WIPING CLOTHS, FILTER MATERIALS AND PROTECTIVE CLOTHING NOT OTHERWISE SPECIFIED 15 01 00 packaging (including separately collected municipal packaging waste) 15 01 10* packaging containing residues of or contaminated by hazardous substances · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. SECTION 14: Transport information · 14.1 UN-Number · ADR, IMDG, IATA
Void
· 14.2 UN proper shipping name · ADR, IMDG, IATA
· 14.3 Transport hazard class(es) · ADR, ADN, IMDG, IATA · Class
· 14.4 Packing group · ADR, IMDG, IATA
Void (Contd. on page 8) GB
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Trade name: ASODUR-GH-S (B-Komp.) (Contd. of page 7)
· 14.5 Environmental hazards:
· 14.6 Special precautions for user
· 14.7 Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable. · UN "Model Regulation":
SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · Directive 2012/18/EU · Named dangerous substances - ANNEX I None of the ingredients is listed. · REGULATION (EC) No 1907/2006 ANNEX XVII Conditions of restriction: 3 · National regulations · Technical instructions (air): · Class Share in % · I 75.0 · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. SECTION 16: Other information These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H332 Harmful if inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 May cause respiratory irritation. H351 Suspected of causing cancer. H373 May cause damage to organs through prolonged or repeated exposure. · Department issuing data specification sheet: Environment protection department. · Contact: Mr. Guido Herfort · Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative Acute Tox. 4: Acute toxicity - inhalation – Category 4 Skin Irrit. 2: Skin corrosion/irritation – Category 2 Eye Irrit. 2: Serious eye damage/eye irritation – Category 2 Resp. Sens. 1: Respiratory sensitisation – Category 1 (Contd. on page 9) GB
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Trade name: ASODUR-GH-S (B-Komp.) (Contd. of page 8) Skin Sens. 1: Skin sensitisation – Category 1 Carc. 2: Carcinogenicity – Category 2 STOT SE 3: Specific target organ toxicity (single exposure) – Category 3 STOT RE 2: Specific target organ toxicity (repeated exposure) – Category 2 GB