Page 1/8
Safety data sheet according to 1907/2006/EC, Article 31 Printing date 06.05.2019 *
Version number 20
Revision: 06.05.2019
SECTION 1: Identification of the substance/mixture and of the company/ undertaking · 1.1 Product identifier · Trade name: ASODUR-K-4031 (B-Komp.)(INDUBOND-VK 4031 (B-Komp.)) · 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture Hardening agent/ Curing agent · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: SCHOMBURG GmbH & Co. KG Aquafinstr. 2-8 D-32760 Detmold Germany ---------------------------------------------Tel: ++49 (0)5231/953-00 Fax: ++49 (0)5231/953-123 email: info@schomburg.de web: www.schomburg.de · Informing department: Product Safety Department Tel: ++49 (0)5231/953-193 Fax: ++49 (0)5231/953-106 email: guido.herfort@schomburg.de
*
SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 GHS07 Skin Irrit. 2 H315 Causes skin irritation. Eye Irrit. 2 H319 Causes serious eye irritation. Skin Sens. 1 H317 May cause an allergic skin reaction. · 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the CLP regulation. · Hazard pictograms GHS07 · Signal word Warning · Hazard-determining components of labelling: 3-aminomethyl-3,5,5-trimethylcyclohexylamine triethylenetetramine 4,4'-Isopropylidenediphenol, oligomeric reaction products with 1-chloro-2.3epoxypropane, reaction products with triethlenetetramine 4,4'-Isopropylidendiphenol, oligomeric reaction products with 1-chloro-2,3-epoxypropane, reaction products with 3-aminomethyl-3,5,5-trimethylcyclohexylamine · Hazard statements H315 Causes skin irritation. (Contd. on page 2) GB
48.1.33
Page 2/8
Safety data sheet according to 1907/2006/EC, Article 31 Printing date 06.05.2019
Trade name: ASODUR-K-4031 (B-Komp.)(INDUBOND-VK 4031 (B-Komp.)) (Contd. of page 1)
H319 Causes serious eye irritation. H317 May cause an allergic skin reaction. · Precautionary statements P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P280 Wear protective gloves / eye protection / face protection. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P501 Dispose of contents/container in accordance with local/regional/ national/international regulations. · 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. *
SECTION 3: Composition/information on ingredients · 3.2 Chemical characterisation: Mixtures · Description: modified polyamidoamine · Dangerous components: CAS: 100-51-6 Benzyl alcohol EINECS: 202-859-9 Acute Tox. 4, H302; Acute Tox. 4, H332; Eye Irrit. 2, H319
2.5-10%
CAS: 112-24-3 triethylenetetramine <2.5% EINECS: 203-950-6 Skin Corr. 1B, H314; Acute Tox. 4, H302; Acute Tox. 4, H312; Skin Sens. 1, H317; Aquatic Chronic 3, H412 CAS: 2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine EINECS: 220-666-8 Skin Corr. 1B, H314; Eye Dam. 1, H318; Acute Tox. 4, H302; Acute Tox. 4, H312; Skin Sens. 1, H317; Aquatic Chronic 3, H412
<2.5%
CAS: 38294-64-3
4,4'-Isopropylidendiphenol, oligomeric reaction products <0.5% with 1-chloro-2,3-epoxypropane, reaction products with 3aminomethyl-3,5,5-trimethylcyclohexylamine Skin Corr. 1B, H314; Eye Dam. 1, H318; Skin Sens. 1, H317; Aquatic Chronic 3, H412 · Additional information For the wording of the listed hazard phrases refer to section 16. SECTION 4: First aid measures · 4.1 Description of first aid measures · General information Instantly remove any clothing soiled by the product. Personal protection for the First Aider. It is possible to choke in case of vomiting in unconsciousness. Bring unconscious persons into a stable position on side. Keep the respiratory tract free (remove dentures and vomiting). (Contd. on page 3) GB
Page 3/8
Trade name: ASODUR-K-4031 (B-Komp.)(INDUBOND-VK 4031 (B-Komp.)) (Contd. of page 2)
Check the pulse. In case of heart failure you have to make a cardiac massage. In case of stoppage of breathing: artificial respiration. Take up a doctor immediately! · After inhalation Supply fresh air or oxygen; call for doctor. In case of unconsciousness bring patient into stable side position for transport. · After skin contact Instantly wash with water and soap and rinse thoroughly. Change immediately contaminated clothes. · After eye contact Rinse opened eye for several minutes under running water. Then consult doctor. · After swallowing Do not induce vomiting; instantly call for medical help. Show the pack or the label to the doctor. · 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents CO2, extinguishing powder or water jet. Fight larger fires with water jet. · 5.2 Special hazards arising from the substance or mixture Formation of poisonous gases during heating or in fires. In case of strong heat burst- and explosion hazard, the pressure in the container will increase. In case of fire chill the container with water-spray. · 5.3 Advice for firefighters · Protective equipment: Wear self-contained breathing apparatus. · Additional information Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. Follow the emergency-plan. SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Bring persons out of danger. Wear protective equipment. Keep unprotected persons away. · 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. · 6.3 Methods and material for containment and cleaning up: Ensure adequate ventilation. · 6.4 Reference to other sections See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. See Section 13 for information on disposal. GB
(Contd. on page 4)
Page 4/8
Trade name: ASODUR-K-4031 (B-Komp.)(INDUBOND-VK 4031 (B-Komp.)) (Contd. of page 3)
SECTION 7: Handling and storage · 7.1 Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. Prevent formation of aerosols. Keep away from children. · Information about protection against explosions and fires: No special measures required. · 7.2 Conditions for safe storage, including any incompatibilities · Storage · Requirements to be met by storerooms and containers: No special requirements. · Information about storage in one common storage facility: Please follow the rules of the VCI-Storage-Concept for chemicals. · Further information about storage conditions: Keep container tightly sealed. Store in a locked cabinet and out of the reach of children. · 7.3 Specific end use(s) No further relevant information available. *
SECTION 8: Exposure controls/personal protection · Additional information about design of technical systems: It must be possible to wash the skin in the working area. Eye-wash bottle must be available. · 8.1 Control parameters · Components with critical values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. · Additional information: The lists that were valid during the compilation were used as basis. · 8.2 Exposure controls · Personal protective equipment · General protective and hygienic measures The usual precautionary measures should be adhered to in handling the chemicals. Instantly remove any soiled and impregnated garments. Avoid contact with the eyes and skin. Be sure to clean skin thoroughly after work and before breaks. · Breathing equipment: Not required. · Protection of hands: Hand Protection: Nitril-rubber-latex-gloves. · Material of gloves Butyl rubber II R: Thickness ≥ 0,5mm; Break through time ≥ 480 min · Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye protection: Safety glasses · Body protection: Protective work clothing. GB
(Contd. on page 5)
Page 5/8
Trade name: ASODUR-K-4031 (B-Komp.)(INDUBOND-VK 4031 (B-Komp.)) (Contd. of page 4)
SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Appearance: Form: Fluid Colour: According to product specification · Smell: Characteristic · Change in condition Melting point/freezing point: Not determined Initial boiling point and boiling range: Not determined · Flash point:
Not applicable
· Self-inflammability:
Product is not selfigniting.
· Explosive properties:
Product is not explosive.
· Density
not determine
· Solubility in / Miscibility with Water: · 9.2 Other information
Not miscible or difficult to mix No further relevant information available.
SECTION 10: Stability and reactivity · 10.1 Reactivity No further relevant information available. · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · 10.3 Possibility of hazardous reactions Reacts with strong acids and oxidizing agents · 10.4 Conditions to avoid No further relevant information available. · 10.5 Incompatible materials: No further relevant information available. · 10.6 Hazardous decomposition products: No dangerous decomposition products known *
SECTION 11: Toxicological information · 11.1 Information on toxicological effects · Acute toxicity Based on available data, the classification criteria are not met. · LD/LC50 values that are relevant for classification: 100-51-6 Benzyl alcohol Oral LD50 1,570 mg/kg (rats) Inhalative LC50 11 mg/l 112-24-3 triethylenetetramine Oral LD50 1,716.2 mg/kg (rats) Dermal LD50 1,465.4 mg/kg (rabbit) 2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine Oral LD50 1,030 mg/kg (rats) (Contd. on page 6) GB
Page 6/8
Trade name: ASODUR-K-4031 (B-Komp.)(INDUBOND-VK 4031 (B-Komp.)) (Contd. of page 5)
Dermal LD50 1,840 mg/kg (rats) · Primary irritant effect: · Skin corrosion/irritation Causes skin irritation. · Serious eye damage/irritation Causes serious eye irritation. · Respiratory or skin sensitisation May cause an allergic skin reaction. · Additional toxicological information: Sensitizing · CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) · Germ cell mutagenicity Based on available data, the classification criteria are not met. · Carcinogenicity Based on available data, the classification criteria are not met. · Reproductive toxicity Based on available data, the classification criteria are not met. · STOT-single exposure Based on available data, the classification criteria are not met. · STOT-repeated exposure Based on available data, the classification criteria are not met. · Aspiration hazard Based on available data, the classification criteria are not met. *
SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: No further relevant information available. · 12.2 Persistence and degradability No further relevant information available. · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · Additional ecological information: · General notes: Water hazard class 2 (Self-assessment): hazardous for water. Do not allow product to reach ground water, water bodies or sewage system. · 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · 12.6 Other adverse effects No further relevant information available. SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system. · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations.
SECTION 14: Transport information · 14.1 UN-Number · ADR, ADN, IMDG, IATA
Void (Contd. on page 7) GB
Page 7/8
Trade name: ASODUR-K-4031 (B-Komp.)(INDUBOND-VK 4031 (B-Komp.)) (Contd. of page 6)
· 14.2 UN proper shipping name · ADR, ADN, IMDG, IATA
Void
· 14.3 Transport hazard class(es) · ADR, ADN, IMDG, IATA · Class
· 14.4 Packing group · ADR, IMDG, IATA
· 14.5 Environmental hazards: · Marine pollutant:
No
· 14.6 Special precautions for user
Not applicable.
· 14.7 Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable. · UN "Model Regulation":
SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · REGULATION (EC) No 1907/2006 ANNEX XVII Conditions of restriction: 3 · National regulations · Water hazard class: Water hazard class 2 (Self-assessment): hazardous for water. The classification based on german instructions. · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
SECTION 16: Other information These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases H302 Harmful if swallowed. H312 Harmful in contact with skin. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H319 Causes serious eye irritation. H332 Harmful if inhaled. H412 Harmful to aquatic life with long lasting effects. · Department issuing data specification sheet: Environment protection department. · Contact: Mr. Guido Herfort · Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) (Contd. on page 8) GB
Page 8/8
Trade name: ASODUR-K-4031 (B-Komp.)(INDUBOND-VK 4031 (B-Komp.)) (Contd. of page 7) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative Acute Tox. 4: Acute toxicity – Category 4 Skin Corr. 1B: Skin corrosion/irritation – Category 1B Skin Irrit. 2: Skin corrosion/irritation – Category 2 Eye Dam. 1: Serious eye damage/eye irritation – Category 1 Eye Irrit. 2: Serious eye damage/eye irritation – Category 2 Skin Sens. 1: Skin sensitisation – Category 1 Aquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard – Category 3
· * Data compared to the previous version altered. GB