48.0.13
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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 24.01.2019 *
Version number 15
Revision: 24.01.2019
SECTION 1: Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: ASOFLEX-AKB WAND + BODEN (B-Komponente) · Article number: 550150810B · 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture Hardening agent/ Curing agent · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: SCHOMBURG GmbH & Co. KG Aquafinstr. 2-8 D-32760 Detmold Germany ---------------------------------------------Tel: ++49 (0)5231/953-00 Fax: ++49 (0)5231/953-123 email: info@schomburg.de web: www.schomburg.de · Informing department: Product Safety Department Tel: ++49 (0)5231/953-193 Fax: ++49 (0)5231/953-106 email: guido.herfort@schomburg.de
*
SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 GHS08 health hazard Resp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. Carc. 2 H351 Suspected of causing cancer. STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure. GHS07 Acute Tox. 4 Skin Irrit. 2 Eye Irrit. 2 Skin Sens. 1 STOT SE 3
H332 Harmful if inhaled. H315 Causes skin irritation. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction. H335 May cause respiratory irritation.
· 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the CLP regulation. · Hazard pictograms GHS07, GHS08 · Signal word Danger · Hazard-determining components of labelling: diphenylmethane-4,4'-di-isocyanante diphenylmethane-2,4'-diisocyanate diphenylmethanediisocyanate,isomeres and homologues diphenylmethane-2,2'-diisocyanate (Contd. on page 2) GB
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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 24.01.2019
Trade name: ASOFLEX-AKB WAND + BODEN (B-Komponente) (Contd. of page 1)
· Hazard statements H332 Harmful if inhaled. H315 Causes skin irritation. H319 Causes serious eye irritation. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H351 Suspected of causing cancer. H335 May cause respiratory irritation. H373 May cause damage to organs through prolonged or repeated exposure. · Precautionary statements P260 Do not breathe dust/fume/gas/mist/vapours/spray. P280 Wear protective gloves/protective clothing/eye protection/face protection. P284 [In case of inadequate ventilation] wear respiratory protection. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national/ international regulations. · Additional information: Contains isocyanates. May produce an allergic reaction. · 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. *
SECTION 3: Composition/information on ingredients · 3.2 Chemical characterisation: Mixtures · Description: Preparation based on Diphenylmethan-Diisocyanat-Prepolymers. (MDI) · Dangerous components: CAS: 101-68-8 25-50% diphenylmethane-4,4'-di-isocyanante EINECS: 202-966-0 Resp. Sens. 1, H334; Carc. 2, H351; STOT RE 2, H373; Acute Tox. 4, H332; Skin Irrit. 2, H315; Eye Irrit. 2, H319; Skin Sens. 1, H317; STOT SE 3, H335 CAS: 5873-54-1 diphenylmethane-2,4'-diisocyanate 25-50% EINECS: 227-534-9 Resp. Sens. 1, H334; Carc. 2, H351; STOT RE 2, H373; Acute Tox. 4, H332; Skin Irrit. 2, H315; Eye Irrit. 2, H319; Skin Sens. 1, H317; STOT SE 3, H335 CAS: 9016-87-9
diphenylmethanediisocyanate,isomeres and homologues 10-25% Resp. Sens. 1, H334; Carc. 2, H351; STOT RE 2, H373; Acute Tox. 4, H332; Skin Irrit. 2, H315; Eye Irrit. 2, H319; Skin Sens. 1, H317; STOT SE 3, H335
CAS: 2536-05-2 diphenylmethane-2,2'-diisocyanate <2.5% EINECS: 219-799-4 Resp. Sens. 1, H334; Carc. 2, H351; STOT RE 2, H373; Acute Tox. 4, H332; Skin Irrit. 2, H315; Eye Irrit. 2, H319; Skin Sens. 1, H317; STOT SE 3, H335 SECTION 4: First aid measures · 4.1 Description of first aid measures · General information Personal protection for the First Aider. It is possible to choke in case of vomiting in unconsciousness. Bring unconscious persons into a stable position on side. Keep the respiratory tract free (remove dentures and vomiting). Check the pulse. In case of heart failure you have to make a cardiac massage. In case of stoppage (Contd. on page 3) GB
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Trade name: ASOFLEX-AKB WAND + BODEN (B-Komponente) (Contd. of page 2)
of breathing: artificial respiration. Take up a doctor immediately! · After inhalation Supply fresh air or oxygen; call for doctor. · After skin contact Instantly wash with water and soap and rinse thoroughly. Change immediately contaminated clothes. · After eye contact Rinse opened eye for several minutes under running water. Then consult doctor. · After swallowing Do not induce vomiting; instantly call for medical help. Do not give household remedys (milk, alcohol etc.) Show the pack or the label to the doctor. · 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed After seriously exposition the patient should be 48 hours under medical supervision. *
SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents CO2, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-resistant foam. · For safety reasons unsuitable extinguishing agents Water with a full water jet. · 5.2 Special hazards arising from the substance or mixture Formation of poisonous gases during heating or in fires. · 5.3 Advice for firefighters · Protective equipment: Wear self-contained breathing apparatus. · Additional information Cool endangered containers with water spray jet. Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Bring persons out of danger. Wear protective equipment. Keep unprotected persons away. · 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. · 6.3 Methods and material for containment and cleaning up: Ensure adequate ventilation. Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). · 6.4 Reference to other sections See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. See Section 13 for information on disposal.
SECTION 7: Handling and storage · 7.1 Precautions for safe handling Do not breath in aerosole, dust and vapour. Ensure good ventilation/exhaustion at the workplace. Keep away from children. · Information about protection against explosions and fires: No special measures required. · 7.2 Conditions for safe storage, including any incompatibilities · Storage · Requirements to be met by storerooms and containers: No special requirements. Protect against wetness and water. (Contd. on page 4) GB
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Trade name: ASOFLEX-AKB WAND + BODEN (B-Komponente) (Contd. of page 3)
Protect from frost The Product reacts with water and CO2-Gas will be given off. In tight closed containers pressure may arise and the cover can burst. · Information about storage in one common storage facility: Recommended storage conditions: Indoor, Temperature between 10°C-30°C · Further information about storage conditions: Keep container tightly sealed. Store in a locked cabinet and out of the reach of children. · 7.3 Specific end use(s) No further relevant information available. *
SECTION 8: Exposure controls/personal protection · Additional information about design of technical systems: It must be possible to wash the skin in the working area. Eye-wash bottle must be available. · 8.1 Control parameters · Components with critical values that require monitoring at the workplace: 101-68-8 diphenylmethane-4,4'-di-isocyanante (25-50%) WEL Short-term value: 0.07 mg/m³ Long-term value: 0.02 mg/m³ Sen; as -NCO 5873-54-1 diphenylmethane-2,4'-diisocyanate (25-50%) WEL Short-term value: 0.07 mg/m³ Long-term value: 0.02 mg/m³ Sen; as -NCO 9016-87-9 diphenylmethanediisocyanate,isomeres and homologues (10-25%) WEL Short-term value: 0.07 mg/m³ Long-term value: 0.02 mg/m³ Sen; as -NCO 2536-05-2 diphenylmethane-2,2'-diisocyanate (<2.5%) WEL Short-term value: 0.07 mg/m³ Long-term value: 0.02 mg/m³ Sen; as -NCO · Ingredients with biological limit values: 101-68-8 diphenylmethane-4,4'-di-isocyanante (25-50%) BMGV 1 µmol creatinine/mol Medium: urine Sampling time: At the end of the period od exposure Parameter: isocyanate-derived diamine 5873-54-1 diphenylmethane-2,4'-diisocyanate (25-50%) BMGV 1 µmol creatinine/mol Medium: urine Sampling time: At the end of the period od exposure Parameter: isocyanate-derived diamine 2536-05-2 diphenylmethane-2,2'-diisocyanate (<2.5%) BMGV 1 µmol creatinine/mol Medium: urine Sampling time: At the end of the period od exposure Parameter: isocyanate-derived diamine · Additional information: The lists that were valid during the compilation were used as basis. (Contd. on page 5) GB
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Trade name: ASOFLEX-AKB WAND + BODEN (B-Komponente) (Contd. of page 4)
· 8.2 Exposure controls · Personal protective equipment · General protective and hygienic measures The usual precautionary measures should be adhered to in handling the chemicals. Instantly remove any soiled and impregnated garments. Wash hands during breaks and at the end of the work. Avoid contact with the eyes and skin. Be sure to clean skin thoroughly after work and before breaks. · Breathing equipment: Use breathing protection in case of insufficient ventilation. · Protection of hands: Hand Protection: Nitril-rubber-latex-gloves. · Material of gloves Butyl rubber II R: Thickness ≥ 0,5mm; Break through time ≥ 480 min · Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye protection: Safety glasses · Body protection: Protective work clothing. Contaminated protection clothes must be cleaned carefully before reuse. SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Appearance: Form: Fluid Colour: Dark brown · Smell: earthy, something musty. · Change in condition Melting point/freezing point: Not determined Initial boiling point and boiling range: 190 °C · Flash point:
180 °C
· Ignition temperature:
400 °C
· Self-inflammability:
Product is not selfigniting.
· Explosive properties:
Product is not explosive.
· Steam pressure:
Not determined.
· Density at 20 °C
1.22 g/cm³
· Solubility in / Miscibility with Water:
react with water
· Viscosity: dynamic at 20 °C: kinematic:
22.5 mPas Not determined.
· Solvent content: Solids content: · 9.2 Other information
0.0 % No further relevant information available.
SECTION 10: Stability and reactivity · 10.1 Reactivity No further relevant information available. (Contd. on page 6) GB
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Trade name: ASOFLEX-AKB WAND + BODEN (B-Komponente) (Contd. of page 5)
· 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · 10.3 Possibility of hazardous reactions No dangerous reactions known · 10.4 Conditions to avoid No further relevant information available. · 10.5 Incompatible materials: No further relevant information available. · 10.6 Hazardous decomposition products: No dangerous decomposition products known *
SECTION 11: Toxicological information · 11.1 Information on toxicological effects · Acute toxicity Harmful if inhaled. · LD/LC50 values that are relevant for classification: 101-68-8 diphenylmethane-4,4'-di-isocyanante Oral LD50 >5,000 mg/kg (rats) Dermal LD50 >5,000 mg/kg (rabbit) Inhalative LC50/4 h >0.49 mg/l (rats) 9016-87-9 diphenylmethanediisocyanate,isomeres and homologues Oral LD50 >5,000 mg/kg (rats) Dermal LD50 >5,000 mg/kg (rabbit) Inhalative LC50/4 h 490 mg/l (rats) · Primary irritant effect: No irritant action known. · Skin corrosion/irritation Moderate irritated. Animal Experiment shows that materials which knows as "sensitive the respiratory tract" (like Diisocyanate) provoke that. This result shows how important to use always protective clothing. Repeat and/or longer contact can lead to a sentisize of the skin. Causes skin irritation. · Serious eye damage/irritation Causes serious eye irritation. · Respiratory or skin sensitisation May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. · Subacute to chronic toxicity: This Produkt is irritant and sensitization are possible by inhalation: repeated inhalation of steam-concentrations or aerosol about the mentioned limit could be cause to sensitization of the respiratory tract. Following symptomes could be caused amongst others: Irritation of eyes, suffocoating in the chest and difficulties in breathing. Symptoms may occur hours after exposition. In fact of sensitization, persons could be heavily react on minimum MDI-Concentrations. Median lethal dose (4 hours) respirable aerosol: 490 mg/kg (rat) · Additional toxicological information: Sensitizing · CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) · Germ cell mutagenicity Based on available data, the classification criteria are not met. · Carcinogenicity Suspected of causing cancer. · Reproductive toxicity Based on available data, the classification criteria are not met. · STOT-single exposure May cause respiratory irritation. · STOT-repeated exposure May cause damage to organs through prolonged or repeated exposure. (Contd. on page 7) GB
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Trade name: ASOFLEX-AKB WAND + BODEN (B-Komponente) (Contd. of page 6)
· Aspiration hazard Based on available data, the classification criteria are not met. *
SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: 9016-87-9 diphenylmethanediisocyanate,isomeres and homologues LC 0 96 mg/l (zebra danio) >1,000 mg/l (acute fishtoxicity zebrafish) EC50 (3h) > 1,000 mg/l (activated sludge bacteria) · 12.2 Persistence and degradability No further relevant information available. · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · Ecotoxical effects: 9016-87-9 diphenylmethanediisocyanate,isomeres and homologues EC 50 24 mg/l (Daphnia magna) >100 mg/l (E. Coli) · Additional ecological information: · General notes: Water hazard class 1 (Self-assessment): slightly hazardous for water. Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage system. · 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · 12.6 Other adverse effects No further relevant information available.
SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system. · European waste catalogue 08 00 00 WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) OF COATINGS (PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVES, SEALANTS AND PRINTING INKS 08 04 00 wastes from MFSU of adhesives and sealants (including waterproofing products) 08 04 11 adhesive and sealant sludges containing organic solvents or other dangerous substances 07 00 00 WASTES FROM ORGANIC CHEMICAL PROCESSES 07 02 00 wastes from the MFSU of plastics, synthetic rubber and man-made fibres 07 02 99 wastes not otherwise specified · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations.
SECTION 14: Transport information · 14.1 UN-Number · ADR, ADN, IMDG, IATA
Void
· 14.2 UN proper shipping name · ADR
Void (Contd. on page 8) GB
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Trade name: ASOFLEX-AKB WAND + BODEN (B-Komponente) (Contd. of page 7)
· ADN, IMDG, IATA
· 14.3 Transport hazard class(es) · ADR, ADN, IMDG, IATA · Class
· 14.4 Packing group · ADR, IMDG, IATA
· 14.5 Environmental hazards:
Not applicable.
· 14.6 Special precautions for user
· 14.7 Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable.
· Transport/Additional information:
Not dangerous according to the above specifications.
· UN "Model Regulation":
SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · REGULATION (EC) No 1907/2006 ANNEX XVII Conditions of restriction: 3, 56a, 56b, 56c · National regulations · Water hazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water. · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
SECTION 16: Other information These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H332 Harmful if inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 May cause respiratory irritation. H351 Suspected of causing cancer. H373 May cause damage to organs through prolonged or repeated exposure. · Department issuing data specification sheet: Environment protection department. · Contact: Mr. Guido Herfort · Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative Acute Tox. 4: Acute toxicity – Category 4 Skin Irrit. 2: Skin corrosion/irritation – Category 2 Eye Irrit. 2: Serious eye damage/eye irritation – Category 2 (Contd. on page 9) GB
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Trade name: ASOFLEX-AKB WAND + BODEN (B-Komponente) (Contd. of page 8) Resp. Sens. 1: Respiratory sensitisation – Category 1 Skin Sens. 1: Skin sensitisation – Category 1 Carc. 2: Carcinogenicity – Category 2 STOT SE 3: Specific target organ toxicity (single exposure) – Category 3 STOT RE 2: Specific target organ toxicity (repeated exposure) – Category 2
· * Data compared to the previous version altered. GB