SDS_COMBIDIC-2K-CLASSIC (A-Komp.)_-_204912_(8)EN.pdf
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<h1>SDS_COMBIDIC-2K-CLASSIC (A-Komp.)_-_204912_(8)EN.pdf</h1> <p>52.1.9</p> <p>Page 1/7</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 26.03.2021 <br />*</p> <p>Version number 8</p> <p>Revision: 26.03.2021</p> <p>SECTION 1: Identification of the substance/mixture and of the company/undertaking <br />· 1.1 Product identifier <br />· Trade name: COMBIDIC-2K-CLASSIC (A-Komp.) <br />· 1.2 Relevant identified uses of the substance or mixture and uses advised against <br />No further relevant information available. <br />· Application of the substance / the mixture bituminous coating <br />· 1.3 Details of the supplier of the safety data sheet <br />· Manufacturer/Supplier: <br />SCHOMBURG GmbH & Co. KG <br />Aquafinstr. 2-8 <br />D-32760 Detmold <br />Germany <br />---------------------------------------------Tel: ++49 (0)5231/953-00 <br />email: info@schomburg.de <br />web: www.schomburg.de <br />· Informing department: <br />Product Safety Department <br />Tel: ++49 (0)5231/953-193 <br />email: SDB@schomburg.de</p> <p>*</p> <p>SECTION 2: Hazards identification <br />· 2.1 Classification of the substance or mixture <br />· Classification according to Regulation (EC) No 1272/2008 <br />The product is not classified, according to the CLP regulation. <br />· 2.2 Label elements <br />· Labelling according to Regulation (EC) No 1272/2008 Void <br />· Hazard pictograms Void <br />· Signal word Void <br />· Hazard statements Void <br />· Additional information: <br />EUH208 Contains reaction products of paraformaldehyde with 2-hydroxypropylamine (ratio 1:1). May <br />produce an allergic reaction. <br />EUH210 Safety data sheet available on request. <br />· 2.3 Other hazards <br />· Results of PBT and vPvB assessment <br />· PBT: Not applicable. <br />· vPvB: Not applicable.</p> <p>*</p> <p>SECTION 3: Composition/information on ingredients <br />· 3.2 Mixtures <br />· Description: Modified anionic Bitumina-Emulsion. <br />· Dangerous components: <br /><0.5% <br />Index number: 612-291-00-7 reaction products of paraformaldehyde with 2hydroxypropylamine (ratio 1:1) <br />Muta. 2, H341; Carc. 1B, H350; STOT RE 2, H373; <br />Skin <br />Corr. 1C, H314; Eye Dam. 1, H318; <br />Aquatic Chronic 2, <br />H411; <br />Acute Tox. 4, H302; Acute Tox. 4, H332; Skin Sens. <br />1A, H317, EUH071 <br />· Additional information For the wording of the listed hazard phrases refer to section 16. <br />GB</p> <p>(Contd. on page 2)</p> <p>52.1.9</p> <p>Page 2/7</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 26.03.2021</p> <p>Version number 8</p> <p>Revision: 26.03.2021</p> <p>Trade name: COMBIDIC-2K-CLASSIC (A-Komp.) <br />(Contd. of page 1)</p> <p>SECTION 4: First aid measures <br />· 4.1 Description of first aid measures <br />· General information Personal protection for the First Aider. <br />· After inhalation Supply fresh air or oxygen; call for doctor. <br />· After skin contact <br />Don't use solvents to clean the skin. <br />Wash with water and soap. <br />· After eye contact Rinse opened eye for several minutes under running water. <br />· After swallowing <br />Drink copious amounts of water and provide fresh air. Instantly call for doctor. <br />Show the pack or the label to the doctor. <br />· 4.2 Most important symptoms and effects, both acute and delayed <br />No further relevant information available. <br />· 4.3 Indication of any immediate medical attention and special treatment needed <br />No further relevant information available. <br />SECTION 5: Firefighting measures <br />· 5.1 Extinguishing media <br />· Suitable extinguishing agents <br />CO2, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-resistant foam. <br />· 5.2 Special hazards arising from the substance or mixture <br />No further relevant information available. <br />· 5.3 Advice for firefighters <br />· Protective equipment: Wear self-contained breathing apparatus. <br />· Additional information <br />Follow the emergency-plan. <br />Burst- and explosion-danger by increasing pressure. <br />In case of fire chill the container with water spray. <br />SECTION 6: Accidental release measures <br />· 6.1 Personal precautions, protective equipment and emergency procedures <br />Avoid eye- and skin contact. <br />Bring persons out of danger. <br />Wear protective equipment. Keep unprotected persons away. <br />· 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. <br />· 6.3 Methods and material for containment and cleaning up: <br />Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). <br />Solid material can be moved mechanically. <br />Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). <br />· 6.4 Reference to other sections <br />No dangerous materials are released. <br />See Section 7 for information on safe handling <br />See Section 8 for information on personal protection equipment. <br />See Section 13 for information on disposal. <br />*</p> <p>SECTION 7: Handling and storage <br />· 7.1 Precautions for safe handling <br />Keep away from heat and direct sunlight. <br />Do not store open containers. <br />Keep away from children. <br />· Information about protection against explosions and fires: No special measures required. <br />(Contd. on page 3) <br />GB</p> <p>52.1.9</p> <p>Page 3/7</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 26.03.2021</p> <p>Version number 8</p> <p>Revision: 26.03.2021</p> <p>Trade name: COMBIDIC-2K-CLASSIC (A-Komp.) <br />(Contd. of page 2)</p> <p>· 7.2 Conditions for safe storage, including any incompatibilities <br />· Storage <br />· Requirements to be met by storerooms and containers: No special requirements. <br />· Information about storage in one common storage facility: <br />Please follow the rules of the VCI-Storage-Concept for chemicals. <br />· Further information about storage conditions: Protect from frost. <br />· Storage class 12 <br />· 7.3 Specific end use(s) No further relevant information available. <br />*</p> <p>SECTION 8: Exposure controls/personal protection <br />· 8.1 Control parameters <br />· Components with critical values that require monitoring at the workplace: <br />8052-42-4 Asphalt (25-50%) <br />WEL Short-term value: 10 mg/m³ <br />Long-term value: 5 mg/m³ <br />9004-34-6 Cellulose (<2.5%) <br />WEL Short-term value: 20* mg/m³ <br />Long-term value: 10* 4** mg/m³ <br />*inhalable dust **respirable <br />· Additional information: The lists that were valid during the compilation were used as basis. <br />· 8.2 Exposure controls <br />· Appropriate engineering controls <br />It must be possible to wash the skin in the working area. <br />Eye-wash bottle must be available. <br />· Individual protection measures, such as personal protective equipment <br />· General protective and hygienic measures <br />Wash hands during breaks and at the end of the work. <br />The usual precautionary measures should be adhered to in handling the chemicals. <br />Avoid contact with eyes and skin. Change clothes which heavy contaminate with the product. <br />· Breathing equipment: Not required. <br />· Hand protection Hand Protection: Nitril-rubber-latex-gloves. <br />· Material of gloves <br />Nitril-rubber-latex-gloves II R: Thickness 0,5mm; Break through time 480 min <br />The selection of the suitable gloves does not only depend on the material, but also on further marks <br />of quality and varies from manufacturer to manufacturer. As the product is a preparation of several <br />substances, the resistance of the glove material can not be calculated in advance and has therefore <br />to be checked prior to the application. <br />· Penetration time of glove material <br />The exact break trough time has to be found out by the manufacturer of the protective gloves and <br />has to be observed. <br />· Eye/face protection Safety glasses <br />· Body protection: Protective work clothing.</p> <p>*</p> <p>SECTION 9: Physical and chemical properties <br />· 9.1 Information on basic physical and chemical properties <br />· General Information <br />· Physical state <br />Fluid <br />· Colour: <br />Dark brown <br />· Smell: <br />bitumen <br />· Odour threshold: <br />Not determined. <br />(Contd. on page 4) <br />GB</p> <p>52.1.9</p> <p>Page 4/7</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 26.03.2021</p> <p>Version number 8</p> <p>Revision: 26.03.2021</p> <p>Trade name: COMBIDIC-2K-CLASSIC (A-Komp.) <br />(Contd. of page 3)</p> <p>· Melting point/freezing point: <br />· Boiling point or initial boiling point and <br />boiling range <br />· Flammability <br />· Lower and upper explosion limit <br />· Lower: <br />· Upper: <br />· Flash point: <br />· Self-inflammability: <br />· Decomposition temperature: <br />· pH at 20 °C <br />· Viscosity: <br />· Kinematic viscosity <br />· dynamic at 20 °C: <br />· Solubility <br />· Water: <br />· Partition coefficient n-octanol/water (log <br />value) <br />· Steam pressure: <br />· Density and/or relative density <br />· Density at 20 °C <br />· Relative density <br />· Vapour density</p> <p>Not determined <br />Not determined <br />Not applicable. <br />Not determined. <br />Not determined. <br />Not applicable <br />Product is not selfigniting. <br />Not determined. <br />11 <br />Not determined. <br />8,500 mPas <br />miscible <br />Not determined. <br />Not determined. <br />0.7 g/cm³ <br />Not determined. <br />Not determined.</p> <p>· 9.2 Other information <br />· Appearance: <br />· Form: <br />Viscous <br />· Important information on protection of health <br />and environment, and on safety. <br />· Explosive properties: <br />Product is not explosive. <br />· Change in condition <br />· Evaporation rate <br />Not determined. <br />· Information with regard to physical hazard <br />classes <br />· Explosives <br />· Flammable gases <br />· Aerosols <br />· Oxidising gases <br />· Gases under pressure <br />· Flammable liquids <br />· Flammable solids <br />· Self-reactive substances and mixtures <br />· Pyrophoric liquids <br />· Pyrophoric solids <br />· Self-heating substances and mixtures <br />· Substances and mixtures, which emit <br />flammable gases in contact with water <br />· Oxidising liquids <br />· Oxidising solids <br />· Organic peroxides <br />· Corrosive to metals <br />· Desensitised explosives</p> <p>Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void</p> <p>SECTION 10: Stability and reactivity <br />· 10.1 Reactivity No further relevant information available. <br />(Contd. on page 5) <br />GB</p> <p>52.1.9</p> <p>Page 5/7</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 26.03.2021</p> <p>Version number 8</p> <p>Revision: 26.03.2021</p> <p>Trade name: COMBIDIC-2K-CLASSIC (A-Komp.) <br />(Contd. of page 4)</p> <p>· 10.2 Chemical stability <br />· Thermal decomposition / conditions to be avoided: <br />No decomposition if used according to specifications. <br />· 10.3 Possibility of hazardous reactions No dangerous reactions known <br />· 10.4 Conditions to avoid No further relevant information available. <br />· 10.5 Incompatible materials: No further relevant information available. <br />· 10.6 Hazardous decomposition products: No dangerous decomposition products known <br />*</p> <p>SECTION 11: Toxicological information <br />· 11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008 <br />· Acute toxicity <br />· LD/LC50 values that are relevant for classification: <br />8052-42-4 Asphalt <br />Oral <br />LD50 <br />>5,000 mg/kg (rats) (vgl. OECD 401) <br />Dermal LD50 <br />>2,000 mg/kg (rabbit) (vgl. OECD 402) <br />LL/EL/IL50 >1,000 mg/l (algae toxicity) ((72h) QSAR Computer) <br />>1,000 mg/l (Daphnia (acute) toxicity) ((48h) QSAR Computer) <br />>1,000 mg/l (fish toxicity) ((96h) QSAR Computer) <br />1-Propanaminium, 3-amino-N-(carboxymethyl)-N,N-dimethyl-, N-(C12-18(even numbered acyl) <br />derivs., hydroxides, inner salts <br />Oral <br />LD50 <br />2,335 mg/kg (rats) <br />reaction products of paraformaldehyde with 2-hydroxypropylamine (ratio 1:1) <br />Oral <br />LD50 <br />960 mg/kg (rats) (OECD 401) <br />Dermal LD50 <br />>2,000 mg/kg (rats) (OECD 402) <br />· Primary irritant effect: No irritant action known. <br />· Serious eye damage/irritation Irritate-effect is possible. <br />· 11.2 Information on other hazards <br />· Endocrine disrupting properties <br />None of the ingredients is listed.</p> <p>*</p> <p>SECTION 12: Ecological information <br />· 12.1 Toxicity <br />· Aquatic toxicity: <br />8052-42-4 Asphalt <br />LL50 <br />>1,000 mg/l (algae toxicity) ((72h) QSAR Computer) <br />>1,000 mg/l (Daphnia (acute) toxicity) ((48h) QSAR Computer) <br />>1,000 mg/l (fish toxicity) ((96h) QSAR Computer) <br />1-Propanaminium, 3-amino-N-(carboxymethyl)-N,N-dimethyl-, N-(C12-18(even numbered acyl) <br />derivs., hydroxides, inner salts <br />EC 50 <br />1.5 mg/kg /72h (Desmodesmus subspicatus) (DIN 38412 T.9 (analogy)) <br />LC50/96h 1.11 mg/l (Calamus penna) (OECD 203 (analogy)) <br />EC0 <br />3,000 mg/l /16h (Pseudomas putida) <br />EC50 (48h) 6.5 mg/l (Daphnia magna) (OECD 202 (analogy)) <br />LOEC <br />0.56 mg/l /21d (Daphnia magna) (OECD 211 (analogy)) <br />NOEC <br />0.32 mg/l /21d (Daphnia magna) (OECD 211 (analogy)) <br />· 12.2 Persistence and degradability No further relevant information available. <br />· 12.3 Bioaccumulative potential No further relevant information available. <br />· 12.4 Mobility in soil No further relevant information available. <br />(Contd. on page 6) <br />GB</p> <p>52.1.9</p> <p>Page 6/7</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 26.03.2021</p> <p>Version number 8</p> <p>Revision: 26.03.2021</p> <p>Trade name: COMBIDIC-2K-CLASSIC (A-Komp.) <br />(Contd. of page 5)</p> <p>· 12.5 Results of PBT and vPvB assessment <br />· PBT: Not applicable. <br />· vPvB: Not applicable. <br />· 12.6 Endocrine disrupting properties <br />The product does not contain substances with endocrine disrupting properties. <br />· 12.7 Other adverse effects <br />· Additional ecological information: <br />· General notes: Generally not hazardous for water. <br />*</p> <p>SECTION 13: Disposal considerations <br />· 13.1 Waste treatment methods <br />· Recommendation <br />Must not be disposed of together with household garbage. Do not allow product to reach sewage <br />system. <br />· Uncleaned packagings: <br />· Recommendation: Packaging can be reused or recycled after cleaning. <br />· Recommended cleaning agent: Water, if necessary with cleaning agent.</p> <p>*</p> <p>SECTION 14: Transport information <br />· 14.1 UN number or ID number <br />· ADR, ADN, IMDG, IATA</p> <p>Void</p> <p>· 14.2 UN proper shipping name <br />· ADR, ADN, IMDG, IATA</p> <p>Void</p> <p>· 14.3 Transport hazard class(es) <br />· ADR, ADN, IMDG, IATA <br />· Class</p> <p>Void</p> <p>· 14.4 Packing group <br />· ADR, IMDG, IATA</p> <p>Void</p> <p>· 14.5 Environmental hazards:</p> <p>Not applicable.</p> <p>· 14.6 Special precautions for user</p> <p>Not applicable.</p> <p>· 14.7 Maritime transport in bulk according to <br />IMO instruments <br />Not applicable. <br />· UN "Model Regulation":</p> <p>*</p> <p>Void</p> <p>SECTION 15: Regulatory information <br />· 15.1 Safety, health and environmental regulations/legislation specific for the substance or <br />mixture <br />· Directive 2012/18/EU <br />· Named dangerous substances - ANNEX I None of the ingredients is listed. <br />· National regulations <br />· Water hazard class: Generally not hazardous for water. <br />· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. <br />GB</p> <p>(Contd. on page 7)</p> <p>52.1.9</p> <p>Page 7/7</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 26.03.2021</p> <p>Version number 8</p> <p>Revision: 26.03.2021</p> <p>Trade name: COMBIDIC-2K-CLASSIC (A-Komp.) <br />(Contd. of page 6)</p> <p>*</p> <p>SECTION 16: Other information <br />These data are based on our present knowledge. However, they shall not constitute a guarantee for <br />any specific product features and shall not establish a legally valid contractual relationship. <br />· Relevant phrases <br />H302 <br />Harmful if swallowed. <br />H314 <br />Causes severe skin burns and eye damage. <br />H317 <br />May cause an allergic skin reaction. <br />H318 <br />Causes serious eye damage. <br />H332 <br />Harmful if inhaled. <br />H341 <br />Suspected of causing genetic defects. <br />H350 <br />May cause cancer. <br />H373 <br />May cause damage to organs through prolonged or repeated exposure. <br />H411 <br />Toxic to aquatic life with long lasting effects. <br />EUH071 Corrosive to the respiratory tract. <br />· Department issuing data specification sheet: Environment protection department. <br />· Contact: Mr. Guido Herfort <br />· Abbreviations and acronyms: <br />ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning <br />the International Carriage of Dangerous Goods by Road) <br />IMDG: International Maritime Code for Dangerous Goods <br />IATA: International Air Transport Association <br />GHS: Globally Harmonised System of Classification and Labelling of Chemicals <br />EINECS: European Inventory of Existing Commercial Chemical Substances <br />ELINCS: European List of Notified Chemical Substances <br />CAS: Chemical Abstracts Service (division of the American Chemical Society) <br />LC50: Lethal concentration, 50 percent <br />LD50: Lethal dose, 50 percent <br />PBT: Persistent, Bioaccumulative and Toxic <br />vPvB: very Persistent and very Bioaccumulative <br />Acute Tox. 4: Acute toxicity – Category 4 <br />Skin Corr. 1C: Skin corrosion/irritation – Category 1C <br />Eye Dam. 1: Serious eye damage/eye irritation – Category 1 <br />Skin Sens. 1A: Skin sensitisation – Category 1A <br />Muta. 2: Germ cell mutagenicity – Category 2 <br />Carc. 1B: Carcinogenicity – Category 1B <br />STOT RE 2: Specific target organ toxicity (repeated exposure) – Category 2 <br />Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard – Category 2</p> <p>· * Data compared to the previous version altered. <br />GB</p>
