44.4.0
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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 09.05.2017 *
Version number 31
Revision: 09.05.2017
SECTION 1: Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: INDUFLEX-PS (B-Komp.)(INDUFLEX-VK-TKF-2000 mv (B-Komp.)) · 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture hardener component · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: SCHOMBURG GmbH & Co. KG Aquafinstr. 2-8 D-32760 Detmold Germany ---------------------------------------------Tel: ++49 (0)5231/953-00 Fax: ++49 (0)5231/953-123 email: info@schomburg.de web: www.schomburg.de · Informing department: Product Safety Department Tel: ++49 (0)5231/953-193 Fax: ++49 (0)5231/953-106 email: guido.herfort@schomburg.de
*
SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 GHS07 Acute Tox. 4 Skin Sens. 1
H302 Harmful if swallowed. H317 May cause an allergic skin reaction.
Aquatic Chronic 3 H412 Harmful to aquatic life with long lasting effects. · 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the CLP regulation. · Hazard pictograms GHS07 · Signal word Warning · Hazard-determining components of labelling: manganese dioxide zinc bis(diethyldithiocarbamate) · Hazard statements H302 Harmful if swallowed. H317 May cause an allergic skin reaction. H412 Harmful to aquatic life with long lasting effects. · Precautionary statements P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P273 Avoid release to the environment. P280 Wear protective gloves. P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. (Contd. on page 2) GB
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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 09.05.2017
Trade name: INDUFLEX-PS (B-Komp.)(INDUFLEX-VK-TKF-2000 mv (B-Komp.)) (Contd. of page 1)
· 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. *
SECTION 3: Composition/information on ingredients · 3.2 Chemical characterisation: Mixtures · Description: Mixture consisting of the following components. · Dangerous components: CAS: 27138-31-4 oxydipropyl dibenzoate Aquatic Chronic 3, H412
25-50%
CAS: 1313-13-9 manganese dioxide EINECS: 215-202-6 Acute Tox. 4, H302; Acute Tox. 4, H332
< 2.5% CAS: 14324-55-1 zinc bis(diethyldithiocarbamate) EINECS: 238-270-9 Aquatic Acute 1, H400; Aquatic Chronic 1, H410; Acute Tox. 4, H302; Skin Irrit. 2, H315; Eye Irrit. 2, H319; Skin Sens. 1, H317; STOT SE 3, H335 CAS: 7704-34-9 sulfur EINECS: 231-722-6 Skin Irrit. 2, H315 · Additional information For the wording of the listed hazard phrases refer to section 16. *
< 2.5%
SECTION 4: First aid measures · 4.1 Description of first aid measures · General information Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. Personal protection for the First Aider. · After inhalation Supply fresh air or oxygen; call for doctor. · After skin contact Instantly wash with water and soap and rinse thoroughly. · After eye contact Rinse opened eye for several minutes under running water. If symptoms persist, consult doctor. · After swallowing Do not induce vomiting; instantly call for medical help. Show the pack or the label to the doctor. · 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents CO2, extinguishing powder or water jet. Fight larger fires with water jet. · For safety reasons unsuitable extinguishing agents Water with a full water jet. · 5.2 Special hazards arising from the substance or mixture Formation of poisonous gases during heating or in fires. · 5.3 Advice for firefighters · Protective equipment: Wear self-contained breathing apparatus. · Additional information Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. (Contd. on page 3) GB
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Trade name: INDUFLEX-PS (B-Komp.)(INDUFLEX-VK-TKF-2000 mv (B-Komp.)) (Contd. of page 2)
Follow the emergency-plan. SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Bring persons out of danger. Wear protective equipment. Keep unprotected persons away. · 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. · 6.3 Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Ensure adequate ventilation. · 6.4 Reference to other sections See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. See Section 13 for information on disposal. SECTION 7: Handling and storage · 7.1 Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. Keep away from children. · Information about protection against explosions and fires: No special measures required. · 7.2 Conditions for safe storage, including any incompatibilities · Storage · Requirements to be met by storerooms and containers: Store in cool location. · Information about storage in one common storage facility: Please follow the rules of the VCI-Storage-Concept for chemicals. · Further information about storage conditions: Keep container tightly sealed. Store in a locked cabinet and out of the reach of children. · 7.3 Specific end use(s) No further relevant information available. *
SECTION 8: Exposure controls/personal protection · Additional information about design of technical systems: It must be possible to wash the skin in the working area. Eye-wash bottle must be available. · 8.1 Control parameters · Components with critical values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. · Additional information: The lists that were valid during the compilation were used as basis. · 8.2 Exposure controls · Personal protective equipment · General protective and hygienic measures The usual precautionary measures should be adhered to in handling the chemicals. Instantly remove any soiled and impregnated garments. Avoid contact with the eyes and skin. Be sure to clean skin thoroughly after work and before breaks. · Breathing equipment: Not required. · Protection of hands: Hand Protection: Nitril-rubber-latex-gloves. · Material of gloves Butyl rubber II R: Thickness ≥ 0,5mm; Break through time ≥ 480 min (Contd. on page 4) GB
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Trade name: INDUFLEX-PS (B-Komp.)(INDUFLEX-VK-TKF-2000 mv (B-Komp.)) (Contd. of page 3)
· Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye protection: Safety glasses · Body protection: Protective work clothing. *
SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Appearance: Form: Viscous Colour: Dark brown · Smell: Like rotten eggs (mercaptans) · Change in condition Melting point/freezing point: Not determined Initial boiling point and boiling range: Not determined · Flash point:
> 150 °C
· Ignition temperature:
400 °C
· Self-inflammability:
Product is not selfigniting.
· Explosive properties:
Product is not explosive.
· Density at 20 °C
1.81 g/cm³
· Solubility in / Miscibility with Water:
Not miscible or difficult to mix
· Viscosity: dynamic at 20 °C: kinematic: · 9.2 Other information
110000 mPas Not determined. No further relevant information available.
SECTION 10: Stability and reactivity · 10.1 Reactivity No further relevant information available. · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · 10.3 Possibility of hazardous reactions No dangerous reactions known · 10.4 Conditions to avoid No further relevant information available. · 10.5 Incompatible materials: No further relevant information available. · 10.6 Hazardous decomposition products: No dangerous decomposition products known *
SECTION 11: Toxicological information · 11.1 Information on toxicological effects · Acute toxicity Harmful if swallowed. · LD/LC50 values that are relevant for classification: 27138-31-4 oxydipropyl dibenzoate Oral LD50 3914 mg/kg (rats) Dermal LD50 > 2000 mg/kg (rats) (Contd. on page 5) GB
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Trade name: INDUFLEX-PS (B-Komp.)(INDUFLEX-VK-TKF-2000 mv (B-Komp.)) (Contd. of page 4)
Inhalative LC50/4 h >200 mg/l (rats) 14324-55-1 zinc bis(diethyldithiocarbamate) Oral LD50 1400 mg/kg (Maus) 400 - 570 mg/kg (rabbit) 700 - 3530 mg/kg (rats) Dermal LD50 > 3160 mg/kg (rabbit) > 2000 mg/kg (rats) 7704-34-9 sulfur Oral LD50 > 5000 mg/kg (rats) Dermal LD50 > 2000 mg/kg (rats) · Primary irritant effect: · Skin corrosion/irritation Based on available data, the classification criteria are not met. · Serious eye damage/irritation Based on available data, the classification criteria are not met. · Respiratory or skin sensitisation May cause an allergic skin reaction. · CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) · Germ cell mutagenicity Based on available data, the classification criteria are not met. · Carcinogenicity Based on available data, the classification criteria are not met. · Reproductive toxicity Based on available data, the classification criteria are not met. · STOT-single exposure Based on available data, the classification criteria are not met. · STOT-repeated exposure Based on available data, the classification criteria are not met. · Aspiration hazard Based on available data, the classification criteria are not met. *
SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: 14324-55-1 zinc bis(diethyldithiocarbamate) EC 50 19.3 mg/kg (Daphnia (acute) toxicity) · 12.2 Persistence and degradability No further relevant information available. · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · Ecotoxical effects: · Remark: Toxic for fish · Additional ecological information: · General notes: Water hazard class 2 (Self-assessment): hazardous for water. · 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · 12.6 Other adverse effects No further relevant information available. SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system. · European waste catalogue 08 00 00 WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) OF COATINGS (PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVES, SEALANTS AND PRINTING INKS (Contd. on page 6) GB
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Trade name: INDUFLEX-PS (B-Komp.)(INDUFLEX-VK-TKF-2000 mv (B-Komp.)) (Contd. of page 5)
08 04 00 wastes from MFSU of adhesives and sealants (including waterproofing products) 08 04 09* waste adhesives and sealants containing organic solvents or other dangerous substances · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. *
SECTION 14: Transport information · 14.1 UN-Number · ADR, ADN, IMDG, IATA · 14.2 UN proper shipping name · ADR · ADN, IMDG, IATA
Void 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (zinc bis(diethyldithiocarbamate)) Void
· 14.3 Transport hazard class(es) · ADR, ADN, IMDG, IATA · Class
Void
· 14.4 Packing group · ADR, IMDG, IATA
· 14.5 Environmental hazards: · Marine pollutant:
Product contains environmentally hazardous substances: zinc bis(diethyldithiocarbamate), oxydipropyl dibenzoate No
· 14.6 Special precautions for user
Not applicable.
· 14.7 Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable. · UN "Model Regulation":
UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (zinc bis(diethyldithiocarbamate)), 9, III
SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · Directive 2012/18/EU · Qualifying quantity (tonnes) for the application of lower-tier requirements 200 t · Qualifying quantity (tonnes) for the application of upper-tier requirements 500 t · REGULATION (EC) No 1907/2006 ANNEX XVII Conditions of restriction: 3 · National regulations · Technical instructions (air): · Class Share in % · III 40.3 · Water hazard class: Water hazard class 2 (Self-assessment): hazardous for water. The classification based on german instructions. · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. GB
(Contd. on page 7)
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Trade name: INDUFLEX-PS (B-Komp.)(INDUFLEX-VK-TKF-2000 mv (B-Komp.)) (Contd. of page 6)
SECTION 16: Other information These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases H302 Harmful if swallowed. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H332 Harmful if inhaled. H335 May cause respiratory irritation. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects. · Department issuing data specification sheet: Environment protection department. · Contact: Mr. Guido Herfort · Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative Acute Tox. 4: Acute toxicity – Category 4 Skin Irrit. 2: Skin corrosion/irritation – Category 2 Eye Irrit. 2: Serious eye damage/eye irritation – Category 2 Skin Sens. 1: Skin sensitisation – Category 1 STOT SE 3: Specific target organ toxicity (single exposure) – Category 3 Aquatic Acute 1: Hazardous to the aquatic environment - acute aquatic hazard – Category 1 Aquatic Chronic 1: Hazardous to the aquatic environment - long-term aquatic hazard – Category 1 Aquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard – Category 3
· * Data compared to the previous version altered. GB