50.0.4
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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 11.05.2020 *
Version number 11
Revision: 11.05.2020
SECTION 1: Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: Purcolor 5000 · 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture Concrete/Mortar admixtures · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: SCHOMBURG GmbH & Co. KG Aquafinstr. 2-8 D-32760 Detmold Germany ---------------------------------------------Tel: ++49 (0)5231/953-00 Fax: ++49 (0)5231/953-123 email: info@schomburg.de web: www.schomburg.de · Informing department: Product Safety Department Tel: ++49 (0)5231/953-193 Fax: ++49 (0)5231/953-106 email: SDB@schomburg.de SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 GHS05 corrosion Skin Corr. 1A H314 Causes severe skin burns and eye damage. Eye Dam. 1 H318 Causes serious eye damage. · 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the CLP regulation. · Hazard pictograms GHS05 · Signal word Danger · Hazard-determining components of labelling: potassium hydroxide · Hazard statements H314 Causes severe skin burns and eye damage. · Precautionary statements P260 Do not breathe dusts or mists. P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
(Contd. on page 2) GB
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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 11.05.2020
Trade name: Purcolor 5000
P405 P501
(Contd. of page 1)
Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.
· 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. *
SECTION 3: Composition/information on ingredients · 3.2 Chemical characterisation: Mixtures · Description: Aqueous alkalisilicatsolution · Dangerous components: CAS: 1312-76-1 potassium silicate EINECS: 215-199-1 Skin Irrit. 2, H315; Eye Irrit. 2, H319 CAS: 1310-58-3 potassium hydroxide EINECS: 215-181-3 Skin Corr. 1A, H314;
2.5-10% 2.5-10%
Acute Tox. 4, H302
SECTION 4: First aid measures · 4.1 Description of first aid measures · General information Personal protection for the First Aider. Instantly remove any clothing soiled by the product. · After inhalation Supply fresh air; consult doctor in case of symptoms. · After skin contact Instantly wash with water and soap and rinse thoroughly. · After eye contact Rinse opened eye for several minutes under running water. Then consult doctor. · After swallowing Drink copious amounts of water and provide fresh air. Instantly call for doctor. · 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents CO2, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-resistant foam. · 5.2 Special hazards arising from the substance or mixture No further relevant information available. · 5.3 Advice for firefighters · Protective equipment: No special measures required. SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Wear protective equipment. Keep unprotected persons away. · 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. · 6.3 Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Ensure adequate ventilation.
(Contd. on page 3) GB
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· 6.4 Reference to other sections See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. See Section 13 for information on disposal.
(Contd. of page 2)
SECTION 7: Handling and storage · 7.1 Precautions for safe handling No special measures required. · Information about protection against explosions and fires: No special measures required. · 7.2 Conditions for safe storage, including any incompatibilities · Storage · Requirements to be met by storerooms and containers: No special requirements. · Information about storage in one common storage facility: Please follow the rules of the VCI-Storage-Concept for chemicals. · Further information about storage conditions: Keep container tightly sealed. · 7.3 Specific end use(s) No further relevant information available. SECTION 8: Exposure controls/personal protection · Additional information about design of technical systems: No further data; see item 7 MSDS. · 8.1 Control parameters · Components with critical values that require monitoring at the workplace: 1310-58-3 potassium hydroxide (2.5-10%) WEL Short-term value: 2 mg/m³ · Additional information: The lists that were valid during the compilation were used as basis. · 8.2 Exposure controls · Personal protective equipment · General protective and hygienic measures The usual precautionary measures should be adhered to in handling the chemicals. Instantly remove any soiled and impregnated garments. Wash hands during breaks and at the end of the work. Avoid contact with the eyes and skin. · Breathing equipment: Not required. · Protection of hands: Hand Protection: Nitril-rubber-latex-gloves. · Material of gloves Nitril-rubber-latex-gloves II R: Thickness 0,5mm; Break through time 480 min · Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye protection: Safety glasses · Body protection: Protective work clothing. SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Appearance: Form: Fluid (Contd. on page 4) GB
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Trade name: Purcolor 5000 (Contd. of page 3)
Colour: · Smell:
Yellow Characteristic
· pH-value at 20 °C:
12.2
· Change in condition Melting point/freezing point: Not determined Initial boiling point and boiling range: Not determined · Flash point:
>200 °C
· Self-inflammability:
Product is not selfigniting.
· Explosive properties:
Product is not explosive.
· Steam pressure:
Not determined.
· Density at 20 °C
1.038 g/cm³
· Solubility in / Miscibility with Water:
Fully miscible
· Viscosity: dynamic: kinematic: · 9.2 Other information
Not determined. Not determined. No further relevant information available.
SECTION 10: Stability and reactivity · 10.1 Reactivity No further relevant information available. · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · 10.3 Possibility of hazardous reactions No dangerous reactions known · 10.4 Conditions to avoid No further relevant information available. · 10.5 Incompatible materials: No further relevant information available. · 10.6 Hazardous decomposition products: No dangerous decomposition products known SECTION 11: Toxicological information · 11.1 Information on toxicological effects · Acute toxicity Based on available data, the classification criteria are not met. · LD/LC50 values that are relevant for classification: 1312-76-1 potassium silicate Oral LD50 >5,000 mg/kg (rats) (OECD 425) Dermal LD50 >5,000 mg/kg (rats) (vgl. OECD 402) Inhalative LC50/4 h >5 mg/l (rats) (vgl. OECD 403) 1310-58-3 potassium hydroxide Oral LD50 365 mg/kg (rats) 68891-38-3 Fatty acid alcohol C 12/14-1E0-sulfate, sodium salt Oral LD50 >2,000 mg/kg (rats) (Contd. on page 5) GB
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Trade name: Purcolor 5000 (Contd. of page 4)
· Primary irritant effect: · Skin corrosion/irritation Causes severe skin burns and eye damage. · Serious eye damage/irritation Causes serious eye damage. · Respiratory or skin sensitisation Based on available data, the classification criteria are not met. · CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) · Germ cell mutagenicity Based on available data, the classification criteria are not met. · Carcinogenicity Based on available data, the classification criteria are not met. · Reproductive toxicity Based on available data, the classification criteria are not met. · STOT-single exposure Based on available data, the classification criteria are not met. · STOT-repeated exposure Based on available data, the classification criteria are not met. · Aspiration hazard Based on available data, the classification criteria are not met. SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: No further relevant information available. · 12.2 Persistence and degradability No further relevant information available. · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · Additional ecological information: · General notes: Water hazard class 2 (Self-assessment): hazardous for water. Do not allow product to reach ground water, water bodies or sewage system. Danger to drinking water if even small quantities leak into soil. · 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · 12.6 Other adverse effects No further relevant information available. SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system. · European waste catalogue 07 00 00 WASTES FROM ORGANIC CHEMICAL PROCESSES 07 06 00 wastes from the MFSU of fats, grease, soaps, detergents, disinfectants and cosmetics 07 06 99 wastes not otherwise specified · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. · Recommended cleaning agent: Water, if necessary with cleaning agent. SECTION 14: Transport information · 14.1 UN-Number · ADR, IMDG, IATA
UN1814 (Contd. on page 6) GB
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Trade name: Purcolor 5000 (Contd. of page 5)
· 14.2 UN proper shipping name · ADR · IMDG, IATA
1814 POTASSIUM HYDROXIDE SOLUTION mixture POTASSIUM HYDROXIDE SOLUTION mixture
· 14.3 Transport hazard class(es) · ADR, IMDG, IATA
· Class · Label
8 Corrosive substances. 8
· 14.4 Packing group · ADR, IMDG, IATA
II
· 14.5 Environmental hazards:
Not applicable.
· 14.6 Special precautions for user · Kemler Number: · EMS Number: · Segregation groups · Stowage Category · Segregation Code
Warning: Corrosive substances. 80 F-A,S-B Alkalis A SG35 Stow "separated from" SGG1-acids
· 14.7 Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable. · Transport/Additional information: · ADR · Limited quantities (LQ) · Excepted quantities (EQ) · Transport category · Tunnel restriction code · IMDG · Limited quantities (LQ) · Excepted quantities (EQ)
· UN "Model Regulation":
1L Code: E2 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 500 ml 2 E 1L Code: E2 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 500 ml UN 1814 POTASSIUM HYDROXIDE SOLUTION MIXTURE, 8, II
SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · Directive 2012/18/EU · Named dangerous substances - ANNEX I None of the ingredients is listed. · REGULATION (EC) No 1907/2006 ANNEX XVII Conditions of restriction: 3 (Contd. on page 7) GB
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Trade name: Purcolor 5000 (Contd. of page 6)
· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. *
SECTION 16: Other information These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H319 Causes serious eye irritation. · Department issuing data specification sheet: Environment protection department. · Contact: Mr. Guido Herfort · Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative Acute Tox. 4: Acute toxicity - oral – Category 4 Skin Corr. 1A: Skin corrosion/irritation – Category 1A Skin Irrit. 2: Skin corrosion/irritation – Category 2 Eye Dam. 1: Serious eye damage/eye irritation – Category 1 Eye Irrit. 2: Serious eye damage/eye irritation – Category 2
· * Data compared to the previous version altered.
GB